(di-tert-butyl-{1-[(di-tert-butyl-silanyl)-methyl]-allyl}-silanyloxymethyl)-benzene

Base Information

• Chemical Name: (di-tert-butyl-{1-[(di-tert-butyl-silanyl)-methyl]-allyl}-silanyloxymethyl)-benzene
• CAS No.: 871840-36-7
• Molecular Formula: C₂₇H₅₀OSi₂
• Molecular Weight: 446.864
• Mol file: 871840-36-7.mol

Synonyms:(di-tert-butyl-{1-[(di-tert-butyl-silanyl)-methyl]-allyl}-silanyloxymethyl)-benzene

Chemical Property of (di-tert-butyl-{1-[(di-tert-butyl-silanyl)-methyl]-allyl}-silanyloxymethyl)-benzene

Chemical Property:

Purity/Quality:

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

Useful:

Technology Process of (di-tert-butyl-{1-[(di-tert-butyl-silanyl)-methyl]-allyl}-silanyloxymethyl)-benzene

There total 2 articles about (di-tert-butyl-{1-[(di-tert-butyl-silanyl)-methyl]-allyl}-silanyloxymethyl)-benzene which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 70.0%

4-benzyloxybut-1-ene (70388-33-9) + 7,7-di-tert-butyl-7-silabicyclo[4.1.0]heptane (130451-35-3) → (di-tert-butyl-{1-[(di-tert-butyl-silanyl)-methyl]-allyl}-silanyloxymethyl)-benzene (871840-36-7)

Guidance literature:

With silver trifluoroacetate; In benzene; at 50 ℃; for 0.5h;

DOI:10.1021/ol052456x

Reference yield:

benzyl bromide (100-39-0) → (di-tert-butyl-{1-[(di-tert-butyl-silanyl)-methyl]-allyl}-silanyloxymethyl)-benzene (871840-36-7)

Guidance literature:

Multi-step reaction with 2 steps

1: 85 percent / sodium hydride / tetrahydrofuran / 12 h / 20 °C

2: 70 percent / AgO₂CCF₃ / benzene / 0.5 h / 50 °C

With silver trifluoroacetate; sodium hydride; In tetrahydrofuran; benzene;

DOI:10.1021/ol052456x

Reference yield: 89.0%

(di-tert-butyl-{1-[(di-tert-butyl-silanyl)-methyl]-allyl}-silanyloxymethyl)-benzene (871840-36-7) + isocyanate de chlorosulfonyle (1189-71-5) → 4-(benzyloxy-di-tert-butyl-silanyl)-5-[(di-tert-butyl-silanyl)-methyl]-dihydro-furan-2-one

Guidance literature:

(di-tert-butyl-{1-[(di-tert-butyl-silanyl)-methyl]-allyl}-silanyloxymethyl)-benzene; isocyanate de chlorosulfonyle; In dichloromethane; at 0 ℃; for 1h;

With hydrogenchloride; In tetrahydrofuran; at 20 ℃; for 12h;

DOI:10.1021/ol052456x

upstream raw materials:

4-benzyloxybut-1-ene

7,7-di-tert-butyl-7-silabicyclo[4.1.0]heptane

benzyl bromide