NC₅H₄-3-CCo₃(CO)9

Base Information

• Chemical Name: NC₅H₄-3-CCo₃(CO)9
• CAS No.: 217096-53-2
• Molecular Formula: C₁₅H₄Co₃NO₉
• Molecular Weight: 519.178
• Mol file: 217096-53-2.mol

Synonyms:NC₅H₄-3-CCo₃(CO)9

Chemical Property of NC₅H₄-3-CCo₃(CO)9

Chemical Property:

Purity/Quality:

Safty Information:

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MSDS Files:

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Technology Process of NC₅H₄-3-CCo₃(CO)9

There total 1 articles about NC₅H₄-3-CCo₃(CO)9 which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 30.0%

dicobalt octacarbonyl + 3-trichloromethyl-pyridine (3099-50-1) + 2-chloro-5-(Trichloromethyl)-pyridine (69045-78-9) → NC5H3-6-Cl-3-CCo3(CO)9 (217096-52-1) + NC5H4-3-CCo3(CO)9 (217096-53-2)

Guidance literature:

In tetrahydrofuran; Ar-atmosphere; stirring Co-complex with excess of 3-Cl3CC5H4N (contg. 6-chloro-derivative as impurity) for 2.5 h at 55°C, standing (roomtemp., overnight); filtration, addn. into 10% HCl, extn. into CH2Cl2, partial evapn. (reduced pressure), chromy. (Wako-gel C-200, hexane/C6H6=1:1, then C6H6), recrystn. (hexane/CH2Cl2); elem. anal.;

DOI:10.1016/S0022-328X(98)00823-7

upstream raw materials:

3-trichloromethyl-pyridine

2-chloro-5-(Trichloromethyl)-pyridine