Technology Process of 9-(4-methylphenyl)-1,2-dicarba-closo-dodecaborane
There total 2 articles about 9-(4-methylphenyl)-1,2-dicarba-closo-dodecaborane which
guide to synthetic route it.
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synthetic route:
- Guidance literature:
-
With
((C6H5)3P)2PdCl2 or ((C6H5)3P)4Pd;
In
diethyl ether;
refluxed for 25-30 h, inert atm.; addition of water, washing an ether soln. with aq. HCl, water, drying with CaCl2, column chromy. (silica gel, benzene-petroleum ether, 15:85), sublimation (100-120°C, 1 torr), recrystn. (hexane); elem. anal.;
DOI:10.1016/S0022-328X(00)83405-1
- Guidance literature:
-
With
potassium carbonate;
In
diethyl ether; acetone;
at 40 ℃;
for 12h;
Inert atmosphere;
Schlenk technique;
DOI:10.1021/jacs.8b10270
- Guidance literature:
-
With
(1,5-cyclooctadiene)(methoxy)iridium(I) dimer; potassium carbonate; tricyclohexylphosphine;
In
tetrahydrofuran;
at 110 ℃;
for 24h;
under 1140.08 Torr;
Time;
Inert atmosphere;
Sealed tube;
DOI:10.1021/jacs.1c00593
