(S)-1-(tert-butyldimethylsilyloxy)-4-(tert-butyldiphenylsilyloxy)-2-methylbutane

Base Information

Chemical Name:(S)-1-(tert-butyldimethylsilyloxy)-4-(tert-butyldiphenylsilyloxy)-2-methylbutane
CAS No.:270258-44-1
Molecular Formula:C₂₇H₄₄O₂Si₂
Molecular Weight:456.816
Hs Code.:

Synonyms:(S)-1-(tert-butyldimethylsilyloxy)-4-(tert-butyldiphenylsilyloxy)-2-methylbutane

Suppliers and Price of (S)-1-(tert-butyldimethylsilyloxy)-4-(tert-butyldiphenylsilyloxy)-2-methylbutane

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Business phase:: The product has achieved commercial mass production^*data from LookChem market partment

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Chemical Property of (S)-1-(tert-butyldimethylsilyloxy)-4-(tert-butyldiphenylsilyloxy)-2-methylbutane

Chemical Property:

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Technology Process of (S)-1-(tert-butyldimethylsilyloxy)-4-(tert-butyldiphenylsilyloxy)-2-methylbutane

There total 7 articles about (S)-1-(tert-butyldimethylsilyloxy)-4-(tert-butyldiphenylsilyloxy)-2-methylbutane which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 99.0%

: 58479-61-1
tert-butylchlorodiphenylsilane

: 156592-93-7
(3S)-4-<(tert-butyldimethylsilyl)oxy>-3-methylbutanol

: 270258-44-1
(S)-1-(tert-butyldimethylsilyloxy)-4-(tert-butyldiphenylsilyloxy)-2-methylbutane

Guidance literature:: With 1H-imidazole; In N,N-dimethyl-formamide;
DOI:10.1039/a907910f

Reference yield:

: 105859-45-8
(S)-3-(tert-butyldimethylsilyloxy)-2-methylpropan-1-ol

: 270258-44-1
(S)-1-(tert-butyldimethylsilyloxy)-4-(tert-butyldiphenylsilyloxy)-2-methylbutane

Guidance literature:: Multi-step reaction with 5 steps

1: pyridine

2: dimethylsulfoxide

3: DIBAL-H / CH₂Cl₂

4: NaBH₄ / ethanol

5: 99 percent / imidazole / dimethylformamide

With 1H-imidazole; sodium tetrahydroborate; diisobutylaluminium hydride; In pyridine; ethanol; dichloromethane; dimethyl sulfoxide; N,N-dimethyl-formamide; 1: Tosylation / 2: Substitution / 3: Reduction / 4: Reduction / 5: Substitution;
DOI:10.1039/a907910f

Reference yield:

: 105859-44-7
methyl (R)-2-methyl-3-[(tert-butyldimethylsilyl)oxy]propionate

: 270258-44-1
(S)-1-(tert-butyldimethylsilyloxy)-4-(tert-butyldiphenylsilyloxy)-2-methylbutane

Guidance literature:: Multi-step reaction with 6 steps

1: 94 percent / DIBAL-H / CH₂Cl₂

2: pyridine

3: dimethylsulfoxide

4: DIBAL-H / CH₂Cl₂

5: NaBH₄ / ethanol

6: 99 percent / imidazole / dimethylformamide

With 1H-imidazole; sodium tetrahydroborate; diisobutylaluminium hydride; In pyridine; ethanol; dichloromethane; dimethyl sulfoxide; N,N-dimethyl-formamide; 1: Reduction / 2: Tosylation / 3: Substitution / 4: Reduction / 5: Reduction / 6: Substitution;
DOI:10.1039/a907910f