CID 16219793

Base Information

• Chemical Name: CID 16219793
• CAS No.: 553-91-3
• Molecular Formula: C2 H2Li2O4
• Molecular Weight: 101.902
• Hs Code.: 2917 11 00
• European Community (EC) Number: 608-551-4
• Mol file: 553-91-3.mol

Synonyms:30903-87-8

Chemical Property of CID 16219793

Chemical Property:

• Vapor Pressure: 2.51E-06mmHg at 25°C
• Melting Point: 41-45°C(lit.)
• Boiling Point: 365.1 °C at 760 mmHg
• Flash Point: 188.8 °C
• PSA: 80.26000
• Density: 0.99g/mL±0.002g/mLat 20°C
• LogP: -3.51380
• Storage Temp.: Store below +30°C.
• Solubility.: 66g/l
• Water Solubility.: Soluble in water.
• Hydrogen Bond Donor Count: 2
• Hydrogen Bond Acceptor Count: 4
• Rotatable Bond Count: 1
• Exact Mass: 97.01131198
• Heavy Atom Count: 7
• Complexity: 71.5

Purity/Quality:

97% ^*data from raw suppliers

Lithium oxalate ^*data from reagent suppliers

Safty Information:

• Pictogram(s): C
• Hazard Codes: C,Xn
• Statements: 21/22-34-63
• Safety Statements: 26-27-36/37/39-45-24/25

MSDS Files:

SDS file from LookChem

Total 1 MSDS from other Authors

Useful:

• Canonical SMILES: [Li].C(=O)(C(=O)O)O
• Uses: Lithium oxalate is used as lithium battery electrolyte. It is also used as an analytical reagent and reducing reagent. Further, it is used as an intermediate in the manufacture of other chemicals such as pharmaceuticals, agrochemicals, dyestuffs and in organic synthesis. Oxalic acid dilithium salt may be used to prepare lithium tetrafluorooxalatophosphate, an electrolyte for Li-ion batteries with better thermal stability.

Technology Process of CID 16219793

There total 23 articles about CID 16219793 which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield:

lithium hydroxide monohydrate (1310-66-3) + boric acid (11113-50-1,14635-83-7) + oxalic acid (144-62-7,97993-78-7) → lithium oxalate (553-91-3) + lithium bis[1,2-oxalato(2-)-O,O'] borate (244761-29-3)

Guidance literature:

at 110 ℃; for 6h; Sealed tube;

DOI:10.1039/c5ra18520c

Reference yield:

oxalic acid (144-62-7,97993-78-7) → lithium oxalate (553-91-3)

Guidance literature:

With lithium hydroxide; In water; at 70 - 100 ℃; pH=7.2; pH-value; Temperature; Industrial scale;

Reference yield:

carbon dioxide (124-38-9,18923-20-1) → lithium oxalate (553-91-3)

Guidance literature:

With lithium tetrafluoroborate; triangular rhodium complex * (BPh₄)2; In acetonitrile; Yield given; electrochemical reduction;

DOI:10.1246/cl.1994.2175

upstream raw materials:

methylammonium carbonate

carbon dioxide

(tert-butoxycarbonyl-ethyl-amino)-oxo-acetic acid ethyl ester

[(3-bromo-propyl)-tert-butoxycarbonyl-amino]-oxo-acetic acid ethyl ester

Downstream raw materials:

carbonic-acid

lithium carbonate

pyrographite

tetraphenylarsonium (2,2'-bipyrimidine)bis(oxalato)chromate(III) monohydrate