[dicarbonyl(2-diphenylphosphinomethylpyridine)iridium(I)]tetrafluoroborate

Base Information

Chemical Name:[dicarbonyl(2-diphenylphosphinomethylpyridine)iridium(I)]tetrafluoroborate
CAS No.:894806-61-2
Molecular Formula:BF₄*C₂₀H₁₆IrNO₂P
Molecular Weight:612.351
Hs Code.:

Synonyms:[dicarbonyl(2-diphenylphosphinomethylpyridine)iridium(I)]tetrafluoroborate

Suppliers and Price of [dicarbonyl(2-diphenylphosphinomethylpyridine)iridium(I)]tetrafluoroborate

Supply Marketing:

Business phase:: The product has achieved commercial mass production^*data from LookChem market partment

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Chemical Property of [dicarbonyl(2-diphenylphosphinomethylpyridine)iridium(I)]tetrafluoroborate

Chemical Property:

Purity/Quality:: 98% ^*data from raw suppliers

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Technology Process of [dicarbonyl(2-diphenylphosphinomethylpyridine)iridium(I)]tetrafluoroborate

There total 1 articles about [dicarbonyl(2-diphenylphosphinomethylpyridine)iridium(I)]tetrafluoroborate which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield:

: [(2-diphenylphosphinomethylpyridine)(η4-cyclooctadiene)iridium(I)] tetrafluoroborate

: 201230-82-2
carbon monoxide

: 894806-61-2
[dicarbonyl(2-diphenylphosphinomethylpyridine)iridium(I)]tetrafluoroborate

Guidance literature:: In neat (no solvent); repeated carbonylation at 1 atm of CO;
DOI:10.1039/b601143h

Reference yield: 72.0%

: 894806-61-2
[dicarbonyl(2-diphenylphosphinomethylpyridine)iridium(I)]tetrafluoroborate

: 107-18-6
allyl alcohol

: [(NC₅H₄CH₂P(C₆H₅)2)Ir(C(O)OC₃H₅)(C₃H₅)]⁽¹⁺⁾*BF₄^(1-)=[(NC₅H₄CH₂P(C₆H₅)2)Ir(C(O)OC₃H₅)(C₃H₅)]BF₄

: [(NC₅H₄CH₂P(C₆H₅)2)Ir(CO)(C(O)OC₃H₅)(C₃H₅)]⁽¹⁺⁾*BF₄^(1-)=[(NC₅H₄CH₂P(C₆H₅)2)Ir(CO)(C(O)OC₃H₅)(C₃H₅)]BF₄

Guidance literature:: In not given; reaction of iridium-carbonyl complex with allyl alcohol (large excess ofalcohol) at ambient temp. for 1 h; mixt. of products, two major species isolated, yield of η3-allyl-η2-allyloxycarbonyl iridium complex depending on solvent (4:1 mixt. of two isomers);
DOI:10.1039/b601143h

Reference yield: 61.0%

: 894806-61-2
[dicarbonyl(2-diphenylphosphinomethylpyridine)iridium(I)]tetrafluoroborate

: 4407-36-7
(2E)-3-phenyl-2-propen-1-ol

: [(NC₅H₄CH₂P(C₆H₅)2)Ir(C(O)OCH₂CHCHC₆H₅)(CO)]

Guidance literature:: With triethylamine; In not given; interaction of cinnamyl alcohol with iridium-carbonyl complex (equimol. amt.) at ambient temp., addn. of NEt3;
DOI:10.1039/b601143h