ω-phenyl isonitrosopropiophenone

Base Information

• Chemical Name: ω-phenyl isonitrosopropiophenone
• CAS No.: 55181-05-0
• Molecular Formula: C₁₅H₁₃NO₂
• Molecular Weight: 239.274
• Mol file: 55181-05-0.mol

Synonyms:ω-phenyl isonitrosopropiophenone

Chemical Property of ω-phenyl isonitrosopropiophenone

Chemical Property:

Purity/Quality:

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

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Technology Process of ω-phenyl isonitrosopropiophenone

There total 13 articles about ω-phenyl isonitrosopropiophenone which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 88.0%

1,1-Dimethoxy-1,3-diphenyl-propan-2-one oxime (132610-70-9) → ω-phenyl isonitrosopropiophenone (55181-05-0)

Guidance literature:

With hydrogenchloride; In chloroform; for 24h; Ambient temperature;

DOI:10.1246/bcsj.63.3579

Reference yield: 78.0%

dihydrochalcone (1083-30-3) → ω-phenyl isonitrosopropiophenone (55181-05-0)

Guidance literature:

With hydrogenchloride; tert-Butyl thionitrate; In tetrahydrofuran; at 0 ℃; for 1h;

DOI:10.1016/S0040-4039(00)99137-8

Reference yield:

2,3-diphenylcyclopropenone oxime hydrochloride → ω-phenyl isonitrosopropiophenone (55181-05-0)

Guidance literature:

Multi-step reaction with 2 steps

1: 41 percent / NaOH / 24 h / 0 °C

2: 88 percent / conc. aq. HCl / CHCl₃ / 24 h / Ambient temperature

With hydrogenchloride; sodium hydroxide; In chloroform;

DOI:10.1246/bcsj.63.3579

upstream raw materials:

methyl nitrite

dihydrochalcone

ethyl nitrite

β-benzoyl-β-nitrostyrene

Downstream raw materials:

1,3-diphenylpropane-1,2-dione

amino-2 diphenyl-1,3 propanol-1

1,2,2-triphenylethan-1-one