4-nitrobenzaldehyde phenylhydrazone

Base Information

• Chemical Name: 4-nitrobenzaldehyde phenylhydrazone
• CAS No.: 2829-27-8
• Molecular Formula: C13H11N3O2
• Molecular Weight: 241.249
• NSC Number: 74709
• Nikkaji Number: J258.379H,J662.799D
• Mol file: 2829-27-8.mol

Synonyms:MLS002693913;NSC74709;Cyto6A6;NSC-74709;4-Nitrobenzaldehyde N-phenyl hydrazone;(E)-4-Nitrobenzaldehyde phenyl hydrazone;N-(4-Nitro-benzylidene)-N'-phenyl-hydrazine;2829-27-8

Chemical Property of 4-nitrobenzaldehyde phenylhydrazone

Chemical Property:

• Vapor Pressure: 7.23E-07mmHg at 25°C
• Boiling Point: 408°Cat760mmHg
• Flash Point: 200.6°C
• Density: 1.2g/cm³
• XLogP3: 3.4
• Hydrogen Bond Donor Count: 1
• Hydrogen Bond Acceptor Count: 4
• Rotatable Bond Count: 3
• Exact Mass: 241.085126602
• Heavy Atom Count: 18
• Complexity: 287

Purity/Quality:

99% ^*data from raw suppliers

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

SDS file from LookChem

Useful:

• Canonical SMILES: C1=CC=C(C=C1)NN=CC2=CC=C(C=C2)[N+](=O)[O-]
• Isomeric SMILES: C1=CC=C(C=C1)N/N=C\C2=CC=C(C=C2)[N+](=O)[O-]

Technology Process of 4-nitrobenzaldehyde phenylhydrazone

There total 17 articles about 4-nitrobenzaldehyde phenylhydrazone which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 99.0%

4-nitrobenzaldehdye (555-16-8) + phenylhydrazine (100-63-0) → 4-nitro-benzaldehyde phenylhydrazone (2829-27-8)

Guidance literature:

With oxaline; In neat (no solvent); at 25 - 30 ℃; for 0.00833333h; Green chemistry;

DOI:10.1016/j.molliq.2013.11.036

Reference yield: 98.0%

phenylhydrazine (100-63-0) + 4-nitrobenzaldehyde oxime (1129-37-9,174848-02-3,20707-69-1) → 4-nitro-benzaldehyde phenylhydrazone (2829-27-8)

Guidance literature:

iron(III) perchlorate; In 1,2-dichloro-ethane; at 20 ℃; for 2h;

DOI:10.1016/j.mencom.2007.05.021

Reference yield: 75.1%

phenylhydrazine hydrochloride (59-88-1) + 4-nitrobenzaldehdye (555-16-8) → 4-nitro-benzaldehyde phenylhydrazone (2829-27-8)

Guidance literature:

With sodium acetate; In 1,4-dioxane; water; at 20 ℃; for 0.333333 - 1h;

DOI:10.1134/S1070363220030044

upstream raw materials:

N-[2-nitro-1-(4-nitro-phenyl)-ethyl]-N'-phenyl-hydrazine

4-nitrobenzaldehdye

phenylhydrazine

4-nitrobenzaldehyde semicarbazone

Downstream raw materials:

2-morpholino-1-(4-nitro-phenyl)-ethanone-phenylhydrazone

4-amino-benzaldehyde phenylhydrazone

3-(4-nitrophenyl)-1,6-diphenyl-4-tosyl-1,4,5,6-tetrahydro-1,2,4-triazine

2-(4-nitrobenzylidene)-1-benzyl-1-phenylhydrazine