(R)-{2-[(phenylmethoxy)methyl]oxiran-2-yl}(triphenylmethoxy)methane

Base Information Edit

Chemical Name:(R)-{2-[(phenylmethoxy)methyl]oxiran-2-yl}(triphenylmethoxy)methane
CAS No.:742104-84-3
Molecular Formula:C₃₀H₂₈O₃
Molecular Weight:436.551
Hs Code.:
Mol file:742104-84-3.mol

Synonyms:(R)-{2-[(phenylmethoxy)methyl]oxiran-2-yl}(triphenylmethoxy)methane

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Chemical Property of (R)-{2-[(phenylmethoxy)methyl]oxiran-2-yl}(triphenylmethoxy)methane Edit

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Technology Process of (R)-{2-[(phenylmethoxy)methyl]oxiran-2-yl}(triphenylmethoxy)methane

There total 2 articles about (R)-{2-[(phenylmethoxy)methyl]oxiran-2-yl}(triphenylmethoxy)methane which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 86.0%

: 100-39-0
benzyl bromide

: 742104-83-2
(R)-{2-[(triphenylmethoxy)methyl]oxiran-2-yl}methanol

: 742104-84-3
(R)-{2-[(phenylmethoxy)methyl]oxiran-2-yl}(triphenylmethoxy)methane

Guidance literature:: With sodium hydride; In N,N-dimethyl-formamide; at 20 ℃; for 1h;
DOI:10.1021/ol0492041

Reference yield:

: 76-83-5
trityl chloride

: 742104-84-3
(R)-{2-[(phenylmethoxy)methyl]oxiran-2-yl}(triphenylmethoxy)methane

Guidance literature:: Multi-step reaction with 3 steps

1: 52 percent / Et₃N / CH₂Cl₂ / 1 h / 20 °C

2: 80 percent / L-(+)-diethyl tartrate; Ti[OiPr]4; t-BuOOH / CH₂Cl₂; various solvent(s) / 8 h / -20 °C

3: 86 percent / NaH / dimethylformamide / 1 h / 20 °C

With titanium(IV) isopropylate; tert.-butylhydroperoxide; diethyl (2R,3R)-tartrate; sodium hydride; triethylamine; In dichloromethane; N,N-dimethyl-formamide; 2: Sharpless epoxidation;
DOI:10.1021/ol0492041