chloromanganese(IV) 5,10,15-tris(pentafluorophenyl)corrolate

Base Information

• Chemical Name: chloromanganese(IV) 5,10,15-tris(pentafluorophenyl)corrolate
• CAS No.: 356042-05-2
• Molecular Formula: C₃₇H₈ClF₁₅MnN₄
• Molecular Weight: 883.864
• Mol file: 356042-05-2.mol

Synonyms:chloromanganese(IV) 5,10,15-tris(pentafluorophenyl)corrolate

Chemical Property of chloromanganese(IV) 5,10,15-tris(pentafluorophenyl)corrolate

Chemical Property:

Purity/Quality:

Safty Information:

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• Hazard Codes: 

MSDS Files:

Useful:

Technology Process of chloromanganese(IV) 5,10,15-tris(pentafluorophenyl)corrolate

There total 2 articles about chloromanganese(IV) 5,10,15-tris(pentafluorophenyl)corrolate which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 99.0%

manganese(III) 5,10,15-tris(pentafluorophenyl)corrolate (262280-87-5) + tris(p-bromophenylammoniumyl) hexachloroantimonate → chloromanganese(IV) 5,10,15-tris(pentafluorophenyl)corrolate (356042-05-2)

Guidance literature:

In hexane; dichloromethane; mixed solns. at room temp.; elem. anal.;

DOI:10.1002/1521-3773(20010601)40:11<2132::AID-ANIE2132>3.0.CO;2-5

Reference yield:

manganese(II) acetate (638-38-0,993-02-2,2180-18-9,15411-95-7,22981-23-3,27004-39-3) + tris(p-bromophenylammoniumyl) hexachloroantimonate + 5,10,15-tris(2,3,4,5,6-pentafluorophenyl)corrole (238402-21-6) → chloromanganese(IV) 5,10,15-tris(pentafluorophenyl)corrolate (356042-05-2)

Guidance literature:

manganese(II) acetate; 5,10,15-tris(2,3,4,5,6-pentafluorophenyl)corrole; In N,N-dimethyl-formamide; for 0.5h; Inert atmosphere; Reflux;

With diethyl ether;

tris(p-bromophenylammoniumyl) hexachloroantimonate;

DOI:10.1016/j.ica.2018.11.048

upstream raw materials:

manganese(III) 5,10,15-tris(pentafluorophenyl)corrolate

manganese(II) acetate

5,10,15-tris(2,3,4,5,6-pentafluorophenyl)corrole