MANGANESE(II) ACETATE

Base Information

• Chemical Name: MANGANESE(II) ACETATE
• CAS No.: 638-38-0
• Molecular Formula: 2C₂H₃O₂*Mn
• Molecular Weight: 173.027
• Hs Code.: 2915.29
• Mol file: 638-38-0.mol

Synonyms:Aceticacid, manganese(2+) salt (8CI,9CI);Manganese acetate (Mn(OAc)2) (6CI);Diacetylmanganese;Manganese acetate;Manganese diacetate;Manganese(2+)acetate;Manganese(II) acetate;Manganous acetate;

Chemical Property of MANGANESE(II) ACETATE

Chemical Property:

• Appearance/Colour: Pale red crystals
• Vapor Pressure: 13hPa at 25℃
• Melting Point: 180 °C
• Boiling Point: 117.1 °C at 760 mmHg
• Flash Point: 40 °C
• PSA: 52.60000
• Density: 1.589 g/cm³
• LogP: 0.02760
• Storage Temp.: Store below +30°C.
• Sensitive.: Hygroscopic
• Water Solubility.: Soluble in water, methanol and acetic acid.

Purity/Quality:

99.9% ^*data from raw suppliers

Manganese(II) acetate 98% ^*data from reagent suppliers

Safty Information:

• Pictogram(s): Xn
• Hazard Codes: Xn
• Statements: 20/21/22-36/37/38-40
• Safety Statements: 26-27-36/37/39

MSDS Files:

SDS file from LookChem

Useful:

• General Description: Manganese(II) acetate, also known as manganous acetate or manganese diacetate, is a chemical compound used as a source of manganese ions in the template-directed assembly of metallosalen-DNA conjugates. In this context, it facilitates the formation of metal-DNA hybrids, which are valuable for applications such as nucleic acid cleavage, biosensing, and catalytic processes. Its role underscores its utility in biochemical and materials science research involving metal-coordinated nucleic acid systems.

Technology Process of MANGANESE(II) ACETATE

There total 42 articles about MANGANESE(II) ACETATE which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 95.0%

manganese (7439-96-5) → manganese(II) acetate (638-38-0,993-02-2,2180-18-9,15411-95-7,22981-23-3,27004-39-3)

Guidance literature:

With acetic acid; In acetonitrile; Electrolysis; 4.5 h, initial voltage 50 V;

Reference yield:

manganese (II) acetate tetrahydrate (6156-78-1) → manganese(II) acetate (638-38-0,993-02-2,2180-18-9,15411-95-7,22981-23-3,27004-39-3)

Guidance literature:

In not given;

Reference yield:

methyltri(butyl)ammonium permanganate + acetic acid (64-19-7,77671-22-8) → manganese(II) acetate (638-38-0,993-02-2,2180-18-9,15411-95-7,22981-23-3,27004-39-3)

Guidance literature:

With tetra-(n-butyl)ammonium iodide; In dichloromethane; byproducts: tetrabutylammonium triiodide, tetrabutylammonium acetate, methyltributylammonium acetate; addn. of excess tetrabutylammonium iodide and glacial acetic acid to soln. of permanganate, stirring; monitored by UV;

upstream raw materials:

acetic anhydride

manganese (II) acetate tetrahydrate

manganese

acetic acid

Downstream raw materials:

5-chloro-2-pentanone

1-methylcyclobutanol acetate

2-Pentanone

4-oxopentyl acetate

Refernces

Nucleic acid template-directed assembly of metallosalen-DNA conjugates [13]

10.1021/ja0162212

The research focuses on the nucleic acid template-directed assembly of metallosalen-DNA conjugates, aiming to expand the versatility of nucleic acid base pairing for the addressable synthesis of bioconjugates in aqueous solutions. The study demonstrates a unique approach to synthesizing a new class of metal-DNA hybrids, which have potential applications in DNA-organized materials, nucleic acid cleavage and detection strategies, and in vitro evolution of novel ribozymes and deoxyribozymes. The process involves the use of DNA oligonucleotides modified with salicylaldehyde moieties, a complementary nucleic acid template, and the addition of an appropriate metal and diamine to assemble the metallosalen conjugate. Key chemicals used in this process include salicylaldehyde, diamine, metal ions (such as Mn and Ni), ethylenediamine (EN), and manganese(II) acetate (Mn(OAc)2). The conclusions of the research highlight the efficient template-directed synthesis and characterization of metallosalen-DNA conjugates, showcasing their potential for applications in targeted nucleic acid cleavage, biosensors, and catalysis.