manganese(III) 5,10,15-tris(pentafluorophenyl)corrolate

Base Information

• Chemical Name: manganese(III) 5,10,15-tris(pentafluorophenyl)corrolate
• CAS No.: 262280-87-5
• Molecular Formula: C₃₇H₈F₁₅MnN₄
• Molecular Weight: 851.435
• Mol file: 262280-87-5.mol

Synonyms:manganese(III) 5,10,15-tris(pentafluorophenyl)corrolate

Chemical Property of manganese(III) 5,10,15-tris(pentafluorophenyl)corrolate

Chemical Property:

Purity/Quality:

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

Useful:

Technology Process of manganese(III) 5,10,15-tris(pentafluorophenyl)corrolate

There total 12 articles about manganese(III) 5,10,15-tris(pentafluorophenyl)corrolate which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 91.0%

5,10,15-tris(pentafluorophenyl)corrole + manganese (II) acetate tetrahydrate (6156-78-1) → 5,10,15-tris(pentafluorophenyl)corrolato-manganese(III) (262280-87-5)

Guidance literature:

In N,N-dimethyl-formamide; solns. of org. compd. and Mn salt heated to reflux for 10 min; solvent evapd., chromy.;

Reference yield: 91.0%

5,10,15-tris(2,3,4,5,6-pentafluorophenyl)corrole (238402-21-6) → 5,10,15-tris(pentafluorophenyl)corrolato-manganese(III) (262280-87-5)

Guidance literature:

With manganese (II) acetate tetrahydrate; In N,N-dimethyl-formamide; for 0.166667h; Reflux;

DOI:10.1021/ja1050296

Reference yield: 90.0%

manganese (II) acetate tetrahydrate (6156-78-1) + 5,10,15-tris(2,3,4,5,6-pentafluorophenyl)corrole (238402-21-6) → 5,10,15-tris(pentafluorophenyl)corrolato-manganese(III) (262280-87-5)

Guidance literature:

In methanol; for 2h; Reflux;

DOI:10.1142/S1088424614500059

upstream raw materials:

manganese (II) acetate tetrahydrate

5,10,15-tris(pentafluorophenyl)corrolato(oxo)manganese(V)

5,10,15-tris(pentafluorophenyl)corrole manganese(V) (N-2,4,6-trichlorophenyl)

triphenylphosphine

Downstream raw materials:

5,10,15-tris(pentafluorophenyl)corrole manganese(V) (N-2,4,6-trichlorophenyl)

5,10,15-tris(pentafluorophenyl)corrole manganese(V) (N-mesityl)

2,3,7,8,12,13,17,18-octabromo-5,10,15-tris(pentafluorophenyl)corrolato-manganese(III)

5,10,15-tris(pentafluorophenyl)corrolato(oxo)manganese(V)