(E)-4-(tert-Butyl-diphenyl-silanyloxymethyl)-7-trimethylsilanyl-hept-4-ene-2,6-diyn-1-ol

Base Information

Chemical Name:(E)-4-(tert-Butyl-diphenyl-silanyloxymethyl)-7-trimethylsilanyl-hept-4-ene-2,6-diyn-1-ol
CAS No.:144543-10-2
Molecular Formula:C₂₇H₃₄O₂Si₂
Molecular Weight:446.737
Hs Code.:

Synonyms:(E)-4-(tert-Butyl-diphenyl-silanyloxymethyl)-7-trimethylsilanyl-hept-4-ene-2,6-diyn-1-ol

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Chemical Property of (E)-4-(tert-Butyl-diphenyl-silanyloxymethyl)-7-trimethylsilanyl-hept-4-ene-2,6-diyn-1-ol

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Technology Process of (E)-4-(tert-Butyl-diphenyl-silanyloxymethyl)-7-trimethylsilanyl-hept-4-ene-2,6-diyn-1-ol

There total 4 articles about (E)-4-(tert-Butyl-diphenyl-silanyloxymethyl)-7-trimethylsilanyl-hept-4-ene-2,6-diyn-1-ol which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 86.0%

: 124044-22-0
(1,1-dimethylethyl)<(2-bromo-2-pentene-5-trimethylsilyl-4-ynyl)oxy>diphenylsilane

: 107-19-7
propargyl alcohol

: 144543-10-2
(E)-4-(tert-Butyl-diphenyl-silanyloxymethyl)-7-trimethylsilanyl-hept-4-ene-2,6-diyn-1-ol

Guidance literature:: With propylamine; copper(l) iodide; bis(triphenylphosphine)palladium(II)-chloride; In tetrahydrofuran; at 23 ℃; for 14h;

Reference yield:

: 124044-21-9
(Z)-2-Bromo-5-trimethylsilanyl-pent-2-en-4-ynoic acid ethyl ester

: 144543-10-2
(E)-4-(tert-Butyl-diphenyl-silanyloxymethyl)-7-trimethylsilanyl-hept-4-ene-2,6-diyn-1-ol

Guidance literature:: Multi-step reaction with 3 steps

1: 94 percent / diisobutylaluminum hydride / hexane; toluene / a) -78 deg C, 30 min, b) 0 deg C, 30 min

2: 95 percent / 4-(dimethylamino)pyridine, triethylamine / tetrahydrofuran / 3.5 h / 23 °C

3: 86 percent / CuI, bis(triphenylphosphine)palladium(II) chloride, n-propylamine / tetrahydrofuran / 14 h / 23 °C

With propylamine; dmap; copper(l) iodide; bis(triphenylphosphine)palladium(II)-chloride; diisobutylaluminium hydride; triethylamine; In tetrahydrofuran; hexane; toluene;

Reference yield:

: 124044-30-0
(Z)-ethyl 2-bromo-3-ethynyl-(trimethylsilyl)propenoate

: 144543-10-2
(E)-4-(tert-Butyl-diphenyl-silanyloxymethyl)-7-trimethylsilanyl-hept-4-ene-2,6-diyn-1-ol

Guidance literature:: Multi-step reaction with 2 steps

1: 95 percent / 4-(dimethylamino)pyridine, triethylamine / tetrahydrofuran / 3.5 h / 23 °C

2: 86 percent / CuI, bis(triphenylphosphine)palladium(II) chloride, n-propylamine / tetrahydrofuran / 14 h / 23 °C

With propylamine; dmap; copper(l) iodide; bis(triphenylphosphine)palladium(II)-chloride; triethylamine; In tetrahydrofuran;