(cyclopentadienyl)bis(tris(p-fluorophenyl)phosphine)ethyliridium(III) hexafluoroantimonate

Base Information

Chemical Name:(cyclopentadienyl)bis(tris(p-fluorophenyl)phosphine)ethyliridium(III) hexafluoroantimonate
CAS No.:104740-72-9
Molecular Formula:C₄₃H₃₄F₆IrP₂*F₆Sb
Molecular Weight:1154.64
Hs Code.:

Synonyms:(cyclopentadienyl)bis(tris(p-fluorophenyl)phosphine)ethyliridium(III) hexafluoroantimonate

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Chemical Property of (cyclopentadienyl)bis(tris(p-fluorophenyl)phosphine)ethyliridium(III) hexafluoroantimonate

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Technology Process of (cyclopentadienyl)bis(tris(p-fluorophenyl)phosphine)ethyliridium(III) hexafluoroantimonate

There total 1 articles about (cyclopentadienyl)bis(tris(p-fluorophenyl)phosphine)ethyliridium(III) hexafluoroantimonate which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 8.0%

: 16925-25-0
sodium hexafluoroantimonate

: diμ-chlorotetrakis(η2-cyclooctene)diiridium(I)

: sodium cyclopentadienide

: 75-03-6
ethyl iodide

: 18437-78-0
P(p-C₆H₄F)3

: 104740-72-9
(cyclopentadienyl)bis(tris(p-fluorophenyl)phosphine)ethyliridium(III) hexafluoroantimonate

Guidance literature:: In tetrahydrofuran; addn. of NaC5H5 in THF to soln. of (FC6H4)3P and Ir-complex at -78°C, stirring for 12 h; warming to 0°C; adding excess of C2H5I and stirring for 1 h; removal of solvents; addn. of NaSbF6 in (CH3)2CO; stirring at 25°C for 5 min; removal of solvents; washing with H2O (removal in vac. over 25 h); dissolving in a min. vol. of CH2Cl2; recrystn. (Et2O/pentane);
DOI:10.1021/ja00283a015