(1S,4R,8S)-3-oxo-p-menthan-9-oic acid

Base Information

Chemical Name:(1S,4R,8S)-3-oxo-p-menthan-9-oic acid
CAS No.:1157861-49-8
Molecular Formula:C₁₀H₁₆O₃
Molecular Weight:184.235
Hs Code.:

Synonyms:(1S,4R,8S)-3-oxo-p-menthan-9-oic acid

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Business phase:: The product has achieved commercial mass production^*data from LookChem market partment

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Chemical Property of (1S,4R,8S)-3-oxo-p-menthan-9-oic acid

Chemical Property:

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Technology Process of (1S,4R,8S)-3-oxo-p-menthan-9-oic acid

There total 10 articles about (1S,4R,8S)-3-oxo-p-menthan-9-oic acid which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 60.0%

: 132438-03-0
(1S,3R,4R,8S)-3,9-epoxy-p-menthane

: 1157861-49-8
(1S,4R,8S)-3-oxo-p-menthan-9-oic acid

Guidance literature:: With sodium periodate; rhodium(III) chloride hydrate; water; In tetrachloromethane; acetonitrile; at 20 ℃; regioselective reaction;
DOI:10.1016/j.tetasy.2011.07.014

Reference yield:

: C₂₀H₃₇B

: 1157861-49-8
(1S,4R,8S)-3-oxo-p-menthan-9-oic acid

Guidance literature:: Multi-step reaction with 4 steps

1: dihydrogen peroxide; sodium hydroxide / water / 4 h / 30 °C

2: boron trifluoride diethyl etherate / diethyl ether / 20 °C

3: palladium on activated charcoal; hydrogen / ethyl acetate / 1 h / 20 °C / 760.05 Torr

4: sodium periodate; rhodium(III) chloride hydrate; water / tetrachloromethane; acetonitrile / 20 °C

With sodium periodate; rhodium(III) chloride hydrate; palladium on activated charcoal; boron trifluoride diethyl etherate; water; hydrogen; dihydrogen peroxide; sodium hydroxide; In tetrachloromethane; diethyl ether; water; ethyl acetate; acetonitrile;
DOI:10.1016/j.tetasy.2011.07.014

Reference yield:

: (4S)-p-mentha-1,5-dien-9-yl acetate

: 1157861-49-8
(1S,4R,8S)-3-oxo-p-menthan-9-oic acid

Guidance literature:: Multi-step reaction with 4 steps

1: sodium hydroxide / methanol / 20 °C

2: boron trifluoride diethyl etherate / diethyl ether / 20 °C

3: palladium on activated charcoal; hydrogen / ethyl acetate / 1 h / 20 °C / 760.05 Torr

4: sodium periodate; rhodium(III) chloride hydrate; water / tetrachloromethane; acetonitrile / 20 °C

With sodium periodate; rhodium(III) chloride hydrate; palladium on activated charcoal; boron trifluoride diethyl etherate; water; hydrogen; sodium hydroxide; In methanol; tetrachloromethane; diethyl ether; ethyl acetate; acetonitrile;
DOI:10.1016/j.tetasy.2011.07.014