2-[2-azido-1-(3,4-dihydro-2,4-dioxopyrimidin-1(2H)-yl)ethoxy]-3-(triphenylmethoxy)propyl benzoate

Base Information

Chemical Name:2-[2-azido-1-(3,4-dihydro-2,4-dioxopyrimidin-1(2H)-yl)ethoxy]-3-(triphenylmethoxy)propyl benzoate
CAS No.:1610592-76-1
Molecular Formula:C₃₅H₃₁N₅O₆
Molecular Weight:617.661
Hs Code.:

Synonyms:2-[2-azido-1-(3,4-dihydro-2,4-dioxopyrimidin-1(2H)-yl)ethoxy]-3-(triphenylmethoxy)propyl benzoate

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Chemical Property of 2-[2-azido-1-(3,4-dihydro-2,4-dioxopyrimidin-1(2H)-yl)ethoxy]-3-(triphenylmethoxy)propyl benzoate

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Technology Process of 2-[2-azido-1-(3,4-dihydro-2,4-dioxopyrimidin-1(2H)-yl)ethoxy]-3-(triphenylmethoxy)propyl benzoate

There total 6 articles about 2-[2-azido-1-(3,4-dihydro-2,4-dioxopyrimidin-1(2H)-yl)ethoxy]-3-(triphenylmethoxy)propyl benzoate which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 75.0%

: 2-[(2,3-dihydro-7-oxo-7H-[1,3]oxazolo[3,2-a]pyrimidin-3-yl)oxy]-3-(triphenylmethoxy)propyl benzoate

: 1610592-76-1
2-[2-azido-1-(3,4-dihydro-2,4-dioxopyrimidin-1(2H)-yl)ethoxy]-3-(triphenylmethoxy)propyl benzoate

Guidance literature:: With sodium azide; In N,N-dimethyl-formamide; at 70 ℃; for 5h; Inert atmosphere;
DOI:10.1002/hlca.201300289

Reference yield:

: 101527-55-3
2,2'-anhydro-3'-O-(methylsulfonyl)-5'-O-(triphenylmethyl)-2',3'-secouridine

: 1610592-76-1
2-[2-azido-1-(3,4-dihydro-2,4-dioxopyrimidin-1(2H)-yl)ethoxy]-3-(triphenylmethoxy)propyl benzoate

Guidance literature:: Multi-step reaction with 2 steps

1: N,N-dimethyl-formamide / 4 h / 100 °C / Inert atmosphere

2: sodium azide / N,N-dimethyl-formamide / 5 h / 70 °C / Inert atmosphere

With sodium azide; In N,N-dimethyl-formamide;
DOI:10.1002/hlca.201300289

Reference yield:

: 6554-10-5
5'-O-trityluridine

: 1610592-76-1
2-[2-azido-1-(3,4-dihydro-2,4-dioxopyrimidin-1(2H)-yl)ethoxy]-3-(triphenylmethoxy)propyl benzoate

Guidance literature:: Multi-step reaction with 6 steps

1: sodium periodate / 1,4-dioxane; water / 2 h / 20 °C / Inert atmosphere; Darkness

2: sodium tetrahydroborate / 1,4-dioxane / 0.5 h / 20 °C / Inert atmosphere

3: triethylamine / dichloromethane / 0 °C / Inert atmosphere

4: 1,8-diazabicyclo[5.4.0]undec-7-ene / tetrahydrofuran / 2 h / 20 °C / Inert atmosphere

5: N,N-dimethyl-formamide / 4 h / 100 °C / Inert atmosphere

6: sodium azide / N,N-dimethyl-formamide / 5 h / 70 °C / Inert atmosphere

With sodium tetrahydroborate; sodium periodate; sodium azide; 1,8-diazabicyclo[5.4.0]undec-7-ene; triethylamine; In tetrahydrofuran; 1,4-dioxane; dichloromethane; water; N,N-dimethyl-formamide;
DOI:10.1002/hlca.201300289