[(η5-C5Me5)(η2-dppe)Ru(C2-1,4-(C6H4)CN)]

Base Information

Chemical Name:[(η5-C5Me5)(η2-dppe)Ru(C2-1,4-(C6H4)CN)]
CAS No.:479041-93-5
Molecular Formula:C₄₅H₄₃NP₂Ru
Molecular Weight:760.861
Hs Code.:

Synonyms:[(η5-C5Me5)(η2-dppe)Ru(C2-1,4-(C6H4)CN)]

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Chemical Property of [(η5-C5Me5)(η2-dppe)Ru(C2-1,4-(C6H4)CN)]

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Technology Process of [(η5-C5Me5)(η2-dppe)Ru(C2-1,4-(C6H4)CN)]

There total 1 articles about [(η5-C5Me5)(η2-dppe)Ru(C2-1,4-(C6H4)CN)] which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 88.0%

: 583884-57-5
(pentamethylcyclopentadienyl)(1,2-bis(diphenylphosphino)ethane)RuC₂H

: 623-00-7
4-bromobenzenecarbonitrile

: 479041-93-5
[(η5-C5Me5)(η2-dppe)Ru(C2-1,4-(C6H4)CN)]

Guidance literature:: With (P(C₆H₅)3)2PdCl₂; CuI; In further solvent(s); (inert atm., Schlenk) Ru-complex, Pd-complex and CuI were introduced in a Schlenk flask under Ar, bromide was added into HN(CH(CH3)2)2, the mixt. was refluxed for 12 h; the solvent was cryogenically trapped, the residue was extd. with toluene, filtered, evapd., eluted through a neutral alumina column using an n-pentane/diethyl ether gradient followed by repeated methanol washing, dried in vac.; elem. anal.;
DOI:10.1021/om050799t

Reference yield:

: 479041-93-5
[(η5-C5Me5)(η2-dppe)Ru(C2-1,4-(C6H4)CN)]

: 2923-28-6
silver trifluoromethanesulfonate

: [(η5-C5Me5)(η2-dppe)Ru(III)(C2-1,4-(C6H4)CN)][Tf]

Guidance literature:: In dichloromethane; Sonication; a slight excess of silver triflate was added to a soln. of complex in CH2Cl2, the mixt. was sonicated for a few min; not sepd., detected by IR-spectra;
DOI:10.1021/om050799t

Reference yield:

: ferrocenium hexafluorophosphate

: 479041-93-5
[(η5-C5Me5)(η2-dppe)Ru(C2-1,4-(C6H4)CN)]

: [(η5-C5Me5)(η2-dppe)Ru(III)(C2-1,4-(C6H4)CN)]PF6

Guidance literature:: In dichloromethane; 1,2-dichloro-ethane; the Ru(II)-complex was ground with a slight excess of (η5-C5H5)2FePF6 and introduced in a ESR tube under an Ar-filled atmosphere, a 1:1 mixt/ of degassed CH2Cl2/1,2-dichloroethane was transferred to dissolve the solid; not sepd., detected by ESR spectra at 77 K;
DOI:10.1021/om050799t