(3S,4S)-4-Benzyloxy-1-[1,3]dithian-2-yl-6-[(4S,5S)-5-(2-[1,3]dithian-2-yl-ethyl)-2,2-dimethyl-[1,3]dioxolan-4-yl]-hexan-3-ol

Base Information

Chemical Name:(3S,4S)-4-Benzyloxy-1-[1,3]dithian-2-yl-6-[(4S,5S)-5-(2-[1,3]dithian-2-yl-ethyl)-2,2-dimethyl-[1,3]dioxolan-4-yl]-hexan-3-ol
CAS No.:500594-04-7
Molecular Formula:C₂₈H₄₄O₄S₄
Molecular Weight:572.919
Hs Code.:

Synonyms:(3S,4S)-4-Benzyloxy-1-[1,3]dithian-2-yl-6-[(4S,5S)-5-(2-[1,3]dithian-2-yl-ethyl)-2,2-dimethyl-[1,3]dioxolan-4-yl]-hexan-3-ol

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Chemical Property of (3S,4S)-4-Benzyloxy-1-[1,3]dithian-2-yl-6-[(4S,5S)-5-(2-[1,3]dithian-2-yl-ethyl)-2,2-dimethyl-[1,3]dioxolan-4-yl]-hexan-3-ol

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Technology Process of (3S,4S)-4-Benzyloxy-1-[1,3]dithian-2-yl-6-[(4S,5S)-5-(2-[1,3]dithian-2-yl-ethyl)-2,2-dimethyl-[1,3]dioxolan-4-yl]-hexan-3-ol

There total 6 articles about (3S,4S)-4-Benzyloxy-1-[1,3]dithian-2-yl-6-[(4S,5S)-5-(2-[1,3]dithian-2-yl-ethyl)-2,2-dimethyl-[1,3]dioxolan-4-yl]-hexan-3-ol which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield:

: 77-76-9
2,2-dimethoxy-propane

: (3S,4S,7S,8S)-7-Benzyloxy-1,10-bis-[1,3]dithian-2-yl-decane-3,4,8-triol

: 500594-04-7
(3S,4S)-4-Benzyloxy-1-[1,3]dithian-2-yl-6-[(4S,5S)-5-(2-[1,3]dithian-2-yl-ethyl)-2,2-dimethyl-[1,3]dioxolan-4-yl]-hexan-3-ol

Guidance literature:: With (1S)-10-camphorsulfonic acid; In dichloromethane; at 20 ℃; for 1h;
DOI:10.1002/anie.200290038

Reference yield:

: 60391-93-7
(4E,8E)-dodeca-4,8-dienedial

: 500594-04-7
(3S,4S)-4-Benzyloxy-1-[1,3]dithian-2-yl-6-[(4S,5S)-5-(2-[1,3]dithian-2-yl-ethyl)-2,2-dimethyl-[1,3]dioxolan-4-yl]-hexan-3-ol

Guidance literature:: Multi-step reaction with 6 steps

1: 99 percent / 10-camphorsulfonic acid / methanol / 1 h / 20 °C

2: AD-mix-α; MeSO2NH2; H2O / 2-methyl-propan-2-ol / 24 h / 0 °C

3: 10-camphorsulfonic acid / methanol / 3 h / -5 °C

4: 93 percent / NaH / tetrahydrofuran / 16 h / -15 - 20 °C

5: Zn(OTf)2 / 1,2-dichloro-ethane / 2 h / 50 °C

6: 10-camphorsulfonic acid / CH₂Cl₂ / 1 h / 20 °C

With AD-mix-α; methanesulfonamide; (1S)-10-camphorsulfonic acid; water; zinc trifluoromethanesulfonate; sodium hydride; In tetrahydrofuran; methanol; dichloromethane; 1,2-dichloro-ethane; tert-butyl alcohol; 2: Sharpless dihydroxylation;
DOI:10.1002/anie.200290038

Reference yield:

: 63284-80-0
1,1,12,12-tetramethoxy-dodeca-4t,8t-diene

: 500594-04-7
(3S,4S)-4-Benzyloxy-1-[1,3]dithian-2-yl-6-[(4S,5S)-5-(2-[1,3]dithian-2-yl-ethyl)-2,2-dimethyl-[1,3]dioxolan-4-yl]-hexan-3-ol

Guidance literature:: Multi-step reaction with 5 steps

1: AD-mix-α; MeSO2NH2; H2O / 2-methyl-propan-2-ol / 24 h / 0 °C

2: 10-camphorsulfonic acid / methanol / 3 h / -5 °C

3: 93 percent / NaH / tetrahydrofuran / 16 h / -15 - 20 °C

4: Zn(OTf)2 / 1,2-dichloro-ethane / 2 h / 50 °C

5: 10-camphorsulfonic acid / CH₂Cl₂ / 1 h / 20 °C

With AD-mix-α; methanesulfonamide; (1S)-10-camphorsulfonic acid; water; zinc trifluoromethanesulfonate; sodium hydride; In tetrahydrofuran; methanol; dichloromethane; 1,2-dichloro-ethane; tert-butyl alcohol; 1: Sharpless dihydroxylation;
DOI:10.1002/anie.200290038