{[3-bromo-4,5-bis(methoxymethoxy)benzyl]oxy}(tert-butyl)dimethylsilane

Base Information

Chemical Name:{[3-bromo-4,5-bis(methoxymethoxy)benzyl]oxy}(tert-butyl)dimethylsilane
CAS No.:1069118-50-8
Molecular Formula:C₁₇H₂₉BrO₅Si
Molecular Weight:421.404
Hs Code.:

Synonyms:{[3-bromo-4,5-bis(methoxymethoxy)benzyl]oxy}(tert-butyl)dimethylsilane

Suppliers and Price of {[3-bromo-4,5-bis(methoxymethoxy)benzyl]oxy}(tert-butyl)dimethylsilane

Supply Marketing:

Business phase:: The product has achieved commercial mass production^*data from LookChem market partment

Manufacturers and distributors:

Manufacture/Brand
Chemicals and raw materials
Packaging
price

Total 0 raw suppliers

Chemical Property of {[3-bromo-4,5-bis(methoxymethoxy)benzyl]oxy}(tert-butyl)dimethylsilane

Chemical Property:

Purity/Quality:

Safty Information:

Pictogram(s):
Hazard Codes:

MSDS Files:

Useful:

Technology Process of {[3-bromo-4,5-bis(methoxymethoxy)benzyl]oxy}(tert-butyl)dimethylsilane

There total 3 articles about {[3-bromo-4,5-bis(methoxymethoxy)benzyl]oxy}(tert-butyl)dimethylsilane which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 85.0%

: 18162-48-6
tert-butyldimethylsilyl chloride

: 252679-56-4
[3-bromo-4,5-bis(methoxymethoxy)phenyl]methanol

: 1069118-50-8
{[3-bromo-4,5-bis(methoxymethoxy)benzyl]oxy}(tert-butyl)dimethylsilane

Guidance literature:: With 1H-imidazole; In N,N-dimethyl-formamide; at 20 ℃; for 10h; Inert atmosphere;
DOI:10.1002/hlca.200900318

Reference yield:

: 16414-34-9
3-bromo-4,5-dihydroxybenzaldehyde

: 1069118-50-8
{[3-bromo-4,5-bis(methoxymethoxy)benzyl]oxy}(tert-butyl)dimethylsilane

Guidance literature:: Multi-step reaction with 3 steps

1: N-ethyl-N,N-diisopropylamine / tetrahydrofuran / 0 °C / Inert atmosphere

2: sodium tetrahydroborate / methanol / 24 h / 0 - 20 °C / Inert atmosphere

3: 1H-imidazole / dichloromethane / 2 h / 0 °C / Inert atmosphere

With 1H-imidazole; sodium tetrahydroborate; N-ethyl-N,N-diisopropylamine; In tetrahydrofuran; methanol; dichloromethane;
DOI:10.1021/acs.joc.5b02756

Reference yield:

: 156605-28-6
3-bromo-4,5-bis(methoxymethoxy)benzaldehyde

: 1069118-50-8
{[3-bromo-4,5-bis(methoxymethoxy)benzyl]oxy}(tert-butyl)dimethylsilane

Guidance literature:: Multi-step reaction with 2 steps

1: sodium tetrahydroborate / methanol / 24 h / 0 - 20 °C / Inert atmosphere

2: 1H-imidazole / dichloromethane / 2 h / 0 °C / Inert atmosphere

With 1H-imidazole; sodium tetrahydroborate; In methanol; dichloromethane;
DOI:10.1021/acs.joc.5b02756