(1α,2β,3α,4β,6β)-4,6-Diazido-1,2,3-cyclohexantriol

Base Information

• Chemical Name: (1α,2β,3α,4β,6β)-4,6-Diazido-1,2,3-cyclohexantriol
• CAS No.: 90899-14-2
• Molecular Formula: C₆H₁₀N₆O₃
• Molecular Weight: 214.184
• Mol file: 90899-14-2.mol

Synonyms:(1α,2β,3α,4β,6β)-4,6-Diazido-1,2,3-cyclohexantriol

Chemical Property of (1α,2β,3α,4β,6β)-4,6-Diazido-1,2,3-cyclohexantriol

Chemical Property:

Purity/Quality:

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

Useful:

Technology Process of (1α,2β,3α,4β,6β)-4,6-Diazido-1,2,3-cyclohexantriol

There total 19 articles about (1α,2β,3α,4β,6β)-4,6-Diazido-1,2,3-cyclohexantriol which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 100.0%

(+/-)-(1R,2R,3S,4R,6S)-4,6-diazido-2-[(tert-butyldimethylsilyl)oxy]cyclohexane-1,3-diol (727719-91-7) → (1α,2β,3α,4β,6β)-4,6-Diazido-1,2,3-cyclohexantriol (90899-14-2)

Guidance literature:

With hydrogenchloride; In methanol; at 20 ℃;

DOI:10.1021/jo049788k

Reference yield: 90.0%

1,3,6',3”-tetra-azido-kanamycin A (1037515-73-3) → (1α,2β,3α,4β,6β)-4,6-Diazido-1,2,3-cyclohexantriol (90899-14-2)

Guidance literature:

With trimethylsilyl trifluoromethanesulfonate; In acetonitrile; at 20 ℃; for 48h; Solvent;

DOI:10.1246/cl.190772

Reference yield: 90.0%

2-deoxystreptamine (2037-48-1,731753-11-0) → (1α,2β,3α,4β,6β)-4,6-Diazido-1,2,3-cyclohexantriol (90899-14-2)

Guidance literature:

With triflic azide; copper(II) sulfate; triethylamine; In methanol; dichloromethane; at 0 ℃; Inert atmosphere;

DOI:10.1055/s-0030-1260033

upstream raw materials:

(1α,2α,3β,4α,5α)-1,2:4,5-dianhydro-1,2,3,4,5-cyclohexane-pentol

2-deoxystreptamine

(+/-)-(1R,2R,3S,4R,6S)-4,6-diazido-2-[(tert-butyldimethylsilyl)oxy]cyclohexane-1,3-diol

2-deoxystreptamine dihydrobromide

Downstream raw materials:

C₂₈H₃₂N₆O₅

(1α,2β,3α,4β,6β)-4,6-Diamino-1,2,3-cyclohexantriol