diiodocarbonyl{1,1,1-tris((diphenylphosphino)methyl)ethane}ruthenium

Base Information

• Chemical Name: diiodocarbonyl{1,1,1-tris((diphenylphosphino)methyl)ethane}ruthenium
• CAS No.: 99299-46-4
• Molecular Formula: C₄₂H₃₉I₂OP₃Ru
• Molecular Weight: 1007.57
• Mol file: 99299-46-4.mol

Synonyms:diiodocarbonyl{1,1,1-tris((diphenylphosphino)methyl)ethane}ruthenium

Chemical Property of diiodocarbonyl{1,1,1-tris((diphenylphosphino)methyl)ethane}ruthenium

Chemical Property:

Purity/Quality:

Safty Information:

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Technology Process of diiodocarbonyl{1,1,1-tris((diphenylphosphino)methyl)ethane}ruthenium

There total 3 articles about diiodocarbonyl{1,1,1-tris((diphenylphosphino)methyl)ethane}ruthenium which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 71.0%

dicarbonyl{1,1,1-tris((diphenylphosphino)methyl)ethane}ruthenium(0) (37843-33-7) → diiodocarbonyl{1,1,1-tris((diphenylphosphino)methyl)ethane}ruthenium (99299-46-4)

Guidance literature:

With iodine; In dichloromethane; under N2, soln. of I2 in CH2Cl2 added dropwise to soln. of Ru(CO)2(triphos) in CH2Cl2, refluxed for 18 h; ppt. collected, washed with CH2Cl2, dried in vac.; elem. anal.;

Reference yield: 22.0%

sodium hexaflorophosphate + dicarbonyl{1,1,1-tris((diphenylphosphino)methyl)ethane}ruthenium(0) (37843-33-7) + ethyl iodide (75-03-6) → dicarbonylethyl{1,1,1-tris((diphenylphosphino)methyl)ethane}ruthenium(1+) hexafluorophosphate (99299-52-2) + diiodocarbonyl{1,1,1-tris((diphenylphosphino)methyl)ethane}ruthenium (99299-46-4)

Guidance literature:

With trimethylamine N-oxide; In ethanol; dichloromethane; under N2, EtI added to Ru(CO)2(triphos) in CH2Cl2, stirred at room temp. for 5 h, evapd. in vac., taken up in EtOH, RuI2(CO)(triphos) filtered off, Me3NO added to mixt. in CH2Cl2, evapd., dissolved in EtOH, filtered, treated with NaPF6 in EtOH; ppt. collected, washed with EtOH and Et2O, dried at room temp.; elem. anal.;

Reference yield:

dicarbonyl{1,1,1-tris((diphenylphosphino)methyl)ethane}ruthenium(0) (37843-33-7) → diiodocarbonyl{1,1,1-tris((diphenylphosphino)methyl)ethane}ruthenium (99299-46-4) + iododicarbonyl{1,1,1-tris((diphenylphosphino)methyl)ethane}ruthenium(1+) iodide (99299-61-3)

Guidance literature:

With iodine; In dichloromethane; under N2, soln. of I2 in CH2Cl2 added dropwise to soln. of Ru(CO)2(triphos) in CH2Cl2; evapd. at room temp., studied by IR, NMR;

upstream raw materials:

dicarbonyl{1,1,1-tris((diphenylphosphino)methyl)ethane}ruthenium⁽⁰⁾

ethyl iodide