Phenylperfluoroisopropyl sulfide

Base Information

• Chemical Name: Phenylperfluoroisopropyl sulfide
• CAS No.: 65538-01-4
• Molecular Formula: C₉H₅F₇S
• Molecular Weight: 278.194
• Mol file: 65538-01-4.mol

Synonyms:Phenylperfluoroisopropyl sulfide

Chemical Property of Phenylperfluoroisopropyl sulfide

Chemical Property:

Purity/Quality:

Safty Information:

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MSDS Files:

Useful:

Technology Process of Phenylperfluoroisopropyl sulfide

There total 5 articles about Phenylperfluoroisopropyl sulfide which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 78.0%

1,1,1,2,2,3,3-heptafluoro-3-iodo-propane (754-34-7) + thiophenol (108-98-5) → Phenylperfluoroisopropyl sulfide (65538-01-4)

Guidance literature:

With sodium hydroxide; triethylbenzyl ammonium chloride; In diethyl ether; water; for 0.5h; Irradiation;

DOI:10.1016/S0022-1139(00)81521-3

Reference yield: 33.0%

Potassium heptafluorobutyrate (2966-54-3) + diphenyldisulfane (882-33-7) → Phenylperfluoroisopropyl sulfide (65538-01-4) + Heptafluoroisopropyl phenyl sulfide (65799-63-5) + 2,3-difluoro-3-trifluoromethyl-2,3-dihydro-benzo[b]thiophene

Guidance literature:

In N,N-dimethyl-formamide; at 130 ℃; for 6h;

DOI:10.1016/S0022-1139(00)00374-2

Reference yield: 12.0%

potassium thiophenolate (3111-52-2) + heptafluorobutyric anhydride (336-59-4) → Phenylperfluoroisopropyl sulfide (65538-01-4) + 2,2,3,3,4,4,4-Heptafluoro-thiobutyric acid S-phenyl ester (112631-04-6)

Guidance literature:

In 1,1,2-Trichloro-1,2,2-trifluoroethane; at 40 ℃; for 5h;

DOI:10.1246/cl.1987.433

upstream raw materials:

sodium thiophenolate

heptafluoro-n-propyl-p-tolyliodonium chloride

1,1,1,2,2,3,3-heptafluoro-3-iodo-propane

thiophenol

Downstream raw materials:

1-iodo-butane

(n-butylthio)benzene

methyl-phenyl-thioether

diphenyl sulfide