1,3-di-O-benzyl-2-O-(2,3,4,6-tetra-O-acetyl-β-D-glucopyranosyl)-sn-glycerol

Base Information

• Chemical Name: 1,3-di-O-benzyl-2-O-(2,3,4,6-tetra-O-acetyl-β-D-glucopyranosyl)-sn-glycerol
• CAS No.: 157024-66-3
• Molecular Formula: C₃₁H₃₈O₁₂
• Molecular Weight: 602.636
• Mol file: 157024-66-3.mol

Synonyms:1,3-di-O-benzyl-2-O-(2,3,4,6-tetra-O-acetyl-β-D-glucopyranosyl)-sn-glycerol

Chemical Property of 1,3-di-O-benzyl-2-O-(2,3,4,6-tetra-O-acetyl-β-D-glucopyranosyl)-sn-glycerol

Chemical Property:

Purity/Quality:

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

Useful:

Technology Process of 1,3-di-O-benzyl-2-O-(2,3,4,6-tetra-O-acetyl-β-D-glucopyranosyl)-sn-glycerol

There total 2 articles about 1,3-di-O-benzyl-2-O-(2,3,4,6-tetra-O-acetyl-β-D-glucopyranosyl)-sn-glycerol which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 67.0%

dibenzyl glycerol (6972-79-8) + 2,3,4,6-tetra-O-acetyl-α-D-glucopyranosyl bromide (572-09-8) → 1,3-di-O-benzyl-2-O-(2,3,4,6-tetra-O-acetyl-β-D-glucopyranosyl)-sn-glycerol (157024-66-3)

Guidance literature:

With mercury(II) cyanide; mercury dibromide; In acetonitrile; for 19h; Ambient temperature;

DOI:10.1080/00397919408010167

Reference yield: 61.0%

dibenzyl glycerol (6972-79-8) + β-D-glucose pentaacetate (604-69-3) → 1,3-di-O-benzyl-2-O-(2,3,4,6-tetra-O-acetyl-β-D-glucopyranosyl)-sn-glycerol (157024-66-3)

Guidance literature:

With boron trifluoride diethyl etherate; In dichloromethane; for 4h; Ambient temperature;

DOI:10.1080/07328309808007465

Reference yield: 97.0%

1,3-di-O-benzyl-2-O-(2,3,4,6-tetra-O-acetyl-β-D-glucopyranosyl)-sn-glycerol (157024-66-3) → (β,β'-dihydroxy-isopropyl)-(tetra-O-acetyl-β-D-glucopyranoside) (157024-67-4)

Guidance literature:

With hydrogen; palladium on activated charcoal; In methanol; for 0.166667h;

DOI:10.1080/00397919408010167

upstream raw materials:

dibenzyl glycerol

2,3,4,6-tetra-O-acetyl-α-D-glucopyranosyl bromide

β-D-glucose pentaacetate

Downstream raw materials:

(β,β'-dihydroxy-isopropyl)-(tetra-O-acetyl-β-D-glucopyranoside)

1,3-di-O-benzyl-2-O-(β-D-glucopyranosyl)-sn-glycerol

1,3-di-O-benzyl-2-O-(6-O-butanoyl-β-D-glucopyranosyl)-sn-glycerol

1,3-di-O-benzyl-2-O-(6-O-octanoyl-β-D-glucopyranosyl)-sn-glycerol