Ti((μ-H)2BC8H14)3(OEt2)

Base Information

• Chemical Name: Ti((μ-H)2BC8H14)3(OEt2)
• CAS No.: 860623-40-1
• Molecular Formula: C₂₈H₅₈B₃OTi
• Molecular Weight: 491.081
• Mol file: 860623-40-1.mol

Synonyms:Ti((μ-H)2BC8H14)3(OEt2)

Chemical Property of Ti((μ-H)2BC8H14)3(OEt2)

Chemical Property:

Purity/Quality:

Safty Information:

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MSDS Files:

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Technology Process of Ti((μ-H)2BC8H14)3(OEt2)

There total 1 articles about Ti((μ-H)2BC8H14)3(OEt2) which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 42.0%

diethyl ether (60-29-7,927820-24-4) + potassium 9,9-dihydrido-9-boratabicyclononane (76448-06-1) + titanium tetrachloride (7550-45-0) → 9-borabicyclo[3.3.1]nonane dimer (21205-91-4) + Ti((μ-H)2BC8H14)3(OEt2) (860623-40-1)

Guidance literature:

In diethyl ether; byproducts: H2, KCl; under inert atm. soln. K(H2BC8H14) in Et2O was added dropwise to soln. TiCl4 in Et2O (1:1) and stirred at room temp. for 12 h; soln. was filtered and evapd. in vacuo, residue was dissolved in ether and kept at -30°C; elem. anal.;

DOI:10.1021/ic050422f

Reference yield: 90.0%

Ti((μ-H)2BC8H14)3(OEt2) (860623-40-1) + aniline (62-53-3) → Ti((μ-H)2BC8H14)3(PhNH2)

Guidance literature:

In diethyl ether; under inert atm. soln. PhNH2 in Et2O was added dropwise to soln. Ti complex in Et2O and stirred at room temp. for 12 h; solvent was removed in vacuo, residue was dissolved in ether and kept at-30°C; elem. anal.;

DOI:10.1021/ic050422f

Reference yield:

Ti((μ-H)2BC8H14)3(OEt2) (860623-40-1) → 9-borabicyclo[3.3.1]nonane dimer (21205-91-4)

Guidance literature:

In tetrahydrofuran;

DOI:10.1021/ic050422f

upstream raw materials:

diethyl ether

potassium 9,9-dihydrido-9-boratabicyclononane

titanium tetrachloride

Downstream raw materials:

9-borabicyclo[3.3.1]nonane dimer