trans-[Re(2,2':6',2''-terpyridine)(PPh₃)2Br](trifluoromethanesulfonate)

Base Information

Chemical Name:trans-[Re(2,2':6',2''-terpyridine)(PPh₃)2Br](trifluoromethanesulfonate)
CAS No.:220937-17-7
Molecular Formula:CF₃O₃S*C₅₁H₄₁BrN₃P₂Re
Molecular Weight:1173.04
Hs Code.:

trans-[Re(2,2':6',2''-terpyridine)(PPh<sub>3</sub>)2Br](trifluoromethanesulfonate)

Synonyms:trans-[Re(2,2':6',2''-terpyridine)(PPh₃)2Br](trifluoromethanesulfonate)

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Business phase:: The product has achieved commercial mass production^*data from LookChem market partment

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Chemical Property of trans-[Re(2,2':6',2''-terpyridine)(PPh₃)2Br](trifluoromethanesulfonate)

Chemical Property:

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Technology Process of trans-[Re(2,2':6',2''-terpyridine)(PPh₃)2Br](trifluoromethanesulfonate)

There total 1 articles about trans-[Re(2,2':6',2''-terpyridine)(PPh₃)2Br](trifluoromethanesulfonate) which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 82.0%

: 220937-39-3
trans-[Re(2,2':6',2''-terpyridine)(PPh₃)2Br]Br

: 2923-28-6
silver trifluoromethanesulfonate

: 220937-17-7
trans-[Re(2,2':6',2''-terpyridine)(PPh₃)2Br](trifluoromethanesulfonate)

Guidance literature:: In methanol; N2-atmosphere; addn. of AgOTf to soln. of Re-complex, stirring (2 h); concn., filtration, extn. (Me2CO), evapn.; elem. anal.;
DOI:10.1021/om980500p

Reference yield: 93.0%

: 220937-17-7
trans-[Re(2,2':6',2''-terpyridine)(PPh₃)2Br](trifluoromethanesulfonate)

: 100-52-7
benzaldehyde

: 594-09-2
trimethylphosphane

: 220937-26-8
trans-[Re(2,2':6',2''-terpyridine)(PMe3)2(η(2)-benzaldehyde)](trifluoromethanesulfonate)

Guidance literature:: With Zn/Hg; In methanol; N,N-dimethyl acetamide; N2-atmosphere; stirring suspension of Re-complex, 10 equiv. of benzaldehyde and excess Zn/Hg in DMA:MeOH 1:3 for 3 h, filtration off of Zn/Hg, washing (MeOH), addn. of excess PMe3, stirring (1 h at room temp., overnight at 60°C); cooling, filtration, washing (MeOH), evapn., dissoln., pptn. on addn. toEt2O, collection (filtration), washing (MeOH), drying (vac.);
DOI:10.1021/om980500p

Reference yield: 80.0%

: 220937-17-7
trans-[Re(2,2':6',2''-terpyridine)(PPh₃)2Br](trifluoromethanesulfonate)

: 119072-55-8,7188-38-7
tert-butylisonitrile

: 100-52-7
benzaldehyde

: 220937-24-6
trans-[Re(2,2':6',2''-terpyridine)(tert-butylisocyanide)2(η(2)-benzaldehyde)](trifluoromethanesulfonate)

Guidance literature:: With Zn/Hg; In methanol; N,N-dimethyl acetamide; N2-atmosphere; stirring suspension of Re-complex, 10 equiv. of benzaldehyde and excess Zn/Hg in DMA:MeOH 1:3 for 3 h, filtration off of Zn/Hg, washing (MeOH), addn. of excess (t)BuNC, stirring (1 h at room temp., overnight at 60°C); cooling, filtration, washing (MeOH), evapn., dissoln., pptn. on addn. toEt2O, collection (filtration), washing (MeOH), drying (vac.);
DOI:10.1021/om980500p