ruthenium3(carbonyl)7(μ-methylene)(μ3-η3-allenyl(i-Pr))(μ-phosphido(phenyl)2)

Base Information

Chemical Name:ruthenium3(carbonyl)7(μ-methylene)(μ3-η3-allenyl(i-Pr))(μ-phosphido(phenyl)2)
CAS No.:87829-54-7
Molecular Formula:C₂₆H₂₁O₇PRu₃
Molecular Weight:779.632
Hs Code.:

Synonyms:ruthenium3(carbonyl)7(μ-methylene)(μ3-η3-allenyl(i-Pr))(μ-phosphido(phenyl)2)

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Chemical Property of ruthenium3(carbonyl)7(μ-methylene)(μ3-η3-allenyl(i-Pr))(μ-phosphido(phenyl)2)

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Technology Process of ruthenium3(carbonyl)7(μ-methylene)(μ3-η3-allenyl(i-Pr))(μ-phosphido(phenyl)2)

There total 4 articles about ruthenium3(carbonyl)7(μ-methylene)(μ3-η3-allenyl(i-Pr))(μ-phosphido(phenyl)2) which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 81.0%

: 87829-51-4
ruthenium3(carbonyl)8(μ3-η3-allenyl(i-Pr))(μ-phosphido(phenyl)2)

: 420-04-2
CYANAMID

: 87829-54-7
ruthenium3(carbonyl)7(μ-methylene)(μ3-η3-allenyl(i-Pr))(μ-phosphido(phenyl)2)

Guidance literature:: In diethyl ether; n-heptane; byproducts: N2; Under N2, addn. of heptane to Ru3(CO)8(CH2C2(i-Pr))(PPh2), cooling (-30°C), addn. of ethereal diazomethane in portions until total consumption of starting material.; IR, concg., crystn. by refrigeration (-15°C), crystn. is aided by addn. of seed crystal, elem. anal.;

Reference yield: 10.0%

: 186581-53-3,908094-01-9,334-88-3
diazomethane

: Ru3(CO)9{μ3-sigma, η2-CCCHMe2}(μ-PPh2)

: ruthenium3(carbonyl)6(μ-CO)2{μ3-η2-(i-Pr-acetylide)}(μ-phosphido(phenyl)2)

: 87829-54-7
ruthenium3(carbonyl)7(μ-methylene)(μ3-η3-allenyl(i-Pr))(μ-phosphido(phenyl)2)

: 87829-51-4
ruthenium3(carbonyl)8(μ3-η3-allenyl(i-Pr))(μ-phosphido(phenyl)2)

: (μ-H)ruthenium3(carbonyl)7(μ3-η4-(i-Pr)butadienyl)(μ-phosphido(phenyl)2)

Guidance literature:: In diethyl ether; excess of CH2N2 soln. added to complex soln. at -5°C; chromd. (heptane), crystd.;

Reference yield:

: Ru3(CO)9{μ3-sigma, η2-CCCHMe2}(μ-PPh2)

: 15243-33-1
dodecacarbonyl-triangulo-triruthenium

: 87829-54-7
ruthenium3(carbonyl)7(μ-methylene)(μ3-η3-allenyl(i-Pr))(μ-phosphido(phenyl)2)

: 87829-51-4
ruthenium3(carbonyl)8(μ3-η3-allenyl(i-Pr))(μ-phosphido(phenyl)2)

: Ru2(CO)6(μ2-η2-CC-i-Pr)(μ-PPh2)

Guidance literature:: In diethyl ether; n-heptane; Under N2, addn. of heptane to Ru3(CO)9(CC(i-Pr))(PPh2), bubbling of N2 through soln. at 60°C, stirring (6 h), cooling in ice bath, addn. of diazomethane/ether soln..; Concg., chromy. (Florisil, heptane) gives yellow band (Ru3(CO)12, Ru2(CO)6(C2(i-Pr))(PPh2)), gray band of Ru3(CO)7(CH2)(CH2C2(i-Pr))(PPh2) and a maroon band, concg., refrigeration (-15°C), elem. anal.;