di-n-butylzirconium dichloride

Base Information

Chemical Name:di-n-butylzirconium dichloride
CAS No.:223594-30-7
Molecular Formula:C₈H₁₈Cl₂Zr
Molecular Weight:276.361
Hs Code.:

Synonyms:di-n-butylzirconium dichloride

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Chemical Property of di-n-butylzirconium dichloride

Chemical Property:

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Technology Process of di-n-butylzirconium dichloride

There total 1 articles about di-n-butylzirconium dichloride which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield:

: 109-72-8,29786-93-4
n-butyllithium

: 10026-11-6
zirconium(IV) chloride

: 13762-26-0
zirconium chloride

: 223594-30-7
di-n-butylzirconium dichloride

Guidance literature:: In tetrahydrofuran; hexane; byproducts: LiCl; under Ar, ZrCl4 soln. in THF was cooled to -78 °C, 2 equiv. of nBuLi was added in 1.6 M hexane soln., warming to room temp. and stirring for 12 h, reflux for 3 h; solvent was removed, residue was diluted with toluene or hexane;
DOI:10.1016/j.poly.2005.03.020

Reference yield: 95.0%

: 223594-30-7
di-n-butylzirconium dichloride

: 492-70-6,655-48-1,2325-10-2,38270-73-4,52340-78-0,579-43-1
1,2-diphenyl-1,2-ethanediol

: OCHC₆H₅C₆H₅CHOZrCl₂

Guidance literature:: In hexane; benzene; byproducts: LiCl; hexane-benzene suspn. of Zr-complex was reacted with ligand at 50°C under Ar for 1 h; filtered, extd. with benzene, solvent was removed;
DOI:10.1021/om0104621

Reference yield: 75.0%

: 223594-30-7
di-n-butylzirconium dichloride

: 7338-50-3
6-phenylfulvene

: bis(benzylcyclopentadienyl)zirconium dichloride

Guidance literature:: In toluene; byproducts: LiCl; under Ar, 2 equiv. of fulvene-compd. and Zr-compd. were allowed to reactat room temp. in toluene for 1 h and at reflux for 2 h; solvent was removed in vac., solid was washed with pentane, slurrying with toluene, LiCl was filtered off, filtrate was freed from volatiles in vac., Soxhlet extn.;
DOI:10.1016/j.poly.2005.03.020