[ZrCl₂(OC₆H₃(C(CH₃)3)CHN(C₆H₄I))2]

Base Information

Chemical Name:[ZrCl₂(OC₆H₃(C(CH₃)3)CHN(C₆H₄I))2]
CAS No.:1003602-07-0
Molecular Formula:C₃₄H₃₄Cl₂I₂N₂O₂Zr
Molecular Weight:918.595
Hs Code.:

[ZrCl<sub>2</sub>(OC<sub>6</sub>H<sub>3</sub>(C(CH<sub>3</sub>)3)CHN(C<sub>6</sub>H<sub>4</sub>I))2]

Synonyms:[ZrCl₂(OC₆H₃(C(CH₃)3)CHN(C₆H₄I))2]

Suppliers and Price of [ZrCl₂(OC₆H₃(C(CH₃)3)CHN(C₆H₄I))2]

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Chemical Property of [ZrCl₂(OC₆H₃(C(CH₃)3)CHN(C₆H₄I))2]

Chemical Property:

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Technology Process of [ZrCl₂(OC₆H₃(C(CH₃)3)CHN(C₆H₄I))2]

There total 3 articles about [ZrCl₂(OC₆H₃(C(CH₃)3)CHN(C₆H₄I))2] which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield:

: 1003080-30-5
HOC₆H₃(C(CH₃)3)CHN(C₆H₄I)

: 10026-11-6
zirconium(IV) chloride

: 1003602-07-0
[ZrCl₂(OC₆H₃(C(CH₃)3)CHN(C₆H₄I))2]

Guidance literature:: With potassium hydride; In tetrahydrofuran; byproducts: KCl, hydrogen; (Ar); using Schlenk techniques; dissolving of HOC6H3(t-Bu)CHNC6H4I in THF; addn. of suspn. of KH (1 equiv.) in THF; stirring for 1 h at room temp.; addn. of ZrCl4 (0.5 equiv.); stirring for 20 h at room temp.; removal of solvent in vac., addn. of CH2Cl2; filtration over Na2SO4; removal of solvent in vac., addn. of n-pentane; pptn., decanting of mother liquor; washing with n-pentane; drying in vac., elem. anal.;
DOI:10.1016/j.jorganchem.2007.10.001

Reference yield:

: 24623-65-2
3-tert-butyl-2-hydroxybenzaldehyde

: 1003602-07-0
[ZrCl₂(OC₆H₃(C(CH₃)3)CHN(C₆H₄I))2]

Guidance literature:: Multi-step reaction with 2 steps

1.1: toluene-4-sulfonic acid / toluene / 3 h / Reflux; Dean-Stark

2.1: sodium hydride / tetrahydrofuran / 1 h / 20 °C

2.2: 20 h / 20 °C

With sodium hydride; toluene-4-sulfonic acid; In tetrahydrofuran; toluene;
DOI:10.1016/j.jorganchem.2016.07.018

Reference yield:

: 88-18-6
2-tert-Butylphenol

: 1003602-07-0
[ZrCl₂(OC₆H₃(C(CH₃)3)CHN(C₆H₄I))2]

Guidance literature:: Multi-step reaction with 3 steps

1.1: methylmagnesium bromide / tetrahydrofuran; diethyl ether / 2 h / 20 °C

1.2: 2 h / 88 °C

2.1: toluene-4-sulfonic acid / toluene / 3 h / Reflux; Dean-Stark

3.1: sodium hydride / tetrahydrofuran / 1 h / 20 °C

3.2: 20 h / 20 °C

With methylmagnesium bromide; sodium hydride; toluene-4-sulfonic acid; In tetrahydrofuran; diethyl ether; toluene;
DOI:10.1016/j.jorganchem.2016.07.018