5,10,15-tris(pentafluorophenyl)corrole manganese(V) (N-2,4,6-trichlorophenyl)

Base Information

• Chemical Name: 5,10,15-tris(pentafluorophenyl)corrole manganese(V) (N-2,4,6-trichlorophenyl)
• CAS No.: 488090-78-4
• Molecular Formula: C₄₃H₁₀Cl₃F₁₅MnN₅
• Molecular Weight: 1042.86
• Mol file: 488090-78-4.mol

Synonyms:5,10,15-tris(pentafluorophenyl)corrole manganese(V) (N-2,4,6-trichlorophenyl)

Chemical Property of 5,10,15-tris(pentafluorophenyl)corrole manganese(V) (N-2,4,6-trichlorophenyl)

Chemical Property:

Purity/Quality:

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

Useful:

Technology Process of 5,10,15-tris(pentafluorophenyl)corrole manganese(V) (N-2,4,6-trichlorophenyl)

There total 1 articles about 5,10,15-tris(pentafluorophenyl)corrole manganese(V) (N-2,4,6-trichlorophenyl) which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 81.0%

5,10,15-tris(pentafluorophenyl)corrolato-manganese(III) (262280-87-5) + 2-azido-1,3,5-trichlorobenzene (61371-35-5) → 5,10,15-tris(pentafluorophenyl)corrole manganese(V) (N-2,4,6-trichlorophenyl) (488090-78-4)

Guidance literature:

In acetonitrile; Irradiation (UV/VIS); (Ar), photolized for 4-5 days; evapd.(vac.), chromy.(silica gel-12:1 pentane:diethyl ether);

DOI:10.1002/1521-3773(20021004)41:19<3591::aid-anie3591>3.0.co;2-z

Reference yield: 100.0%

5,10,15-tris(pentafluorophenyl)corrole manganese(V) (N-2,4,6-trichlorophenyl) (488090-78-4) + triphenylphosphine (603-35-0) → manganese(III) 5,10,15-tris(pentafluorophenyl)corrole NPPh3(2,4,6-trichlorophenyl) (488090-82-0)

Guidance literature:

In toluene; Irradiation (UV/VIS); (Ar), at 20°C for 10 min;

DOI:10.1002/1521-3773(20021004)41:19<3591::aid-anie3591>3.0.co;2-z

Reference yield: 100.0%

5,10,15-tris(pentafluorophenyl)corrole manganese(V) (N-2,4,6-trichlorophenyl) (488090-78-4) + triethylphosphine (554-70-1) → manganese(III) 5,10,15-tris(pentafluorophenyl)corrple NPEt3(2,4,6-trichlorophenyl) (488090-83-1)

Guidance literature:

In toluene; Irradiation (UV/VIS); (Ar), at 20°C for < 1 min;

DOI:10.1002/1521-3773(20021004)41:19<3591::aid-anie3591>3.0.co;2-z

upstream raw materials:

5,10,15-tris(pentafluorophenyl)corrolato-manganese(III)

2-azido-1,3,5-trichlorobenzene

Downstream raw materials:

5,10,15-tris(pentafluorophenyl)corrolato-manganese(III)

manganese(III) 5,10,15-tris(pentafluorophenyl)corrple NPEt₃(2,4,6-trichlorophenyl)

manganese(III) 5,10,15-tris(pentafluorophenyl)corrole NPPh₃(2,4,6-trichlorophenyl)

Mn(tris(pentafluorophenyl)corrole^(3-))(N(2,4,6-Cl₃C₆H₂)PCy₃)