toluyl 3,4-di-O-acetyl-6-O-tert-butyldimethylsilyl-2-deoxy-(2,2,2-trichloroethyloxycarbonyl)-amino-1-thio-β-D-glucosamine

Base Information

Chemical Name:toluyl 3,4-di-O-acetyl-6-O-tert-butyldimethylsilyl-2-deoxy-(2,2,2-trichloroethyloxycarbonyl)-amino-1-thio-β-D-glucosamine
CAS No.:1487449-30-8
Molecular Formula:C₂₆H₃₈Cl₃NO₈SSi
Molecular Weight:659.1
Hs Code.:

Synonyms:toluyl 3,4-di-O-acetyl-6-O-tert-butyldimethylsilyl-2-deoxy-(2,2,2-trichloroethyloxycarbonyl)-amino-1-thio-β-D-glucosamine

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Chemical Property of toluyl 3,4-di-O-acetyl-6-O-tert-butyldimethylsilyl-2-deoxy-(2,2,2-trichloroethyloxycarbonyl)-amino-1-thio-β-D-glucosamine

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Technology Process of toluyl 3,4-di-O-acetyl-6-O-tert-butyldimethylsilyl-2-deoxy-(2,2,2-trichloroethyloxycarbonyl)-amino-1-thio-β-D-glucosamine

There total 4 articles about toluyl 3,4-di-O-acetyl-6-O-tert-butyldimethylsilyl-2-deoxy-(2,2,2-trichloroethyloxycarbonyl)-amino-1-thio-β-D-glucosamine which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 99.0%

: 1453169-66-8
toluyl 6-O-tert-butyldimethylsilyl-2-deoxy-(2,2,2-trichloroethyloxycarbonyl)amino-1-thio-Β-D-glucosamine

: 108-24-7
acetic anhydride

: 1487449-30-8
toluyl 3,4-di-O-acetyl-6-O-tert-butyldimethylsilyl-2-deoxy-(2,2,2-trichloroethyloxycarbonyl)-amino-1-thio-β-D-glucosamine

Guidance literature:: With pyridine; at 20 ℃; for 3h; Inert atmosphere;
DOI:10.1002/ejoc.201300664

Reference yield:

: 323195-45-5
p-methylphenyl 2-deoxy-2-(2,2,2-trichloroethoxycarbonylamino)-1-thio-β-D-glucopyranoside

: 1487449-30-8
toluyl 3,4-di-O-acetyl-6-O-tert-butyldimethylsilyl-2-deoxy-(2,2,2-trichloroethyloxycarbonyl)-amino-1-thio-β-D-glucosamine

Guidance literature:: Multi-step reaction with 2 steps

1: 1,2-dichloro-ethane / 16 h / Reflux; Inert atmosphere

2: pyridine / 3 h / 20 °C / Inert atmosphere

With pyridine; In 1,2-dichloro-ethane;
DOI:10.1002/ejoc.201300664

Reference yield:

: 18162-48-6
tert-butyldimethylsilyl chloride

: 1487449-30-8
toluyl 3,4-di-O-acetyl-6-O-tert-butyldimethylsilyl-2-deoxy-(2,2,2-trichloroethyloxycarbonyl)-amino-1-thio-β-D-glucosamine

Guidance literature:: Multi-step reaction with 2 steps

1: 1,2-dichloro-ethane / 16 h / Reflux; Inert atmosphere

2: pyridine / 3 h / 20 °C / Inert atmosphere

With pyridine; In 1,2-dichloro-ethane;
DOI:10.1002/ejoc.201300664