Technology Process of [PtBr2(Ph2PCH(CH2Ph)PPh2)]
There total 2 articles about [PtBr2(Ph2PCH(CH2Ph)PPh2)] which
guide to synthetic route it.
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synthetic route:
- Guidance literature:
-
With
lithium hexamethyldisilazane;
In
tetrahydrofuran;
a suspn. of complex was treated with equivalent amt. of base at 20°C for 1.5 h, benzyl chloride added, heated at 45-50°C for 5 h; recrystn. (dichloromethane);
DOI:10.1016/S0020-1693(00)93517-5
- Guidance literature:
-
With
lithium hexamethyldisilazane;
In
tetrahydrofuran;
a soln. of LiN(SiMe3)2 in THF was added to a suspn. of Pt-compd. in THFand the resultant mixt. was stirred at ca. 20°C for 1.5 h; C6H5CH2Br was then added and the mixt. was then stirred at 45-55°C for5 h;; the solvent was then evapd., the residue washed with H2O and dried andthe product extd. with. and recrystd. from CH2Cl2/MeOH; elem.anal.;;
DOI:10.1016/S0020-1693(00)81432-2
![cis-diiodo[1,1'-methylenebis[1,1-diphenylphosphine-κP]]platinum](/Databaselist/images/loading.webp)
