cis-diiodo[1,1'-methylenebis[1,1-diphenylphosphine-κP]]platinum

Base Information

• Chemical Name: cis-diiodo[1,1'-methylenebis[1,1-diphenylphosphine-κP]]platinum
• CAS No.: 64040-32-0
• Molecular Formula: C₂₅H₂₂I₂P₂Pt
• Molecular Weight: 833.286
• Mol file: 64040-32-0.mol

Synonyms:cis-diiodo[1,1'-methylenebis[1,1-diphenylphosphine-κP]]platinum

Chemical Property of cis-diiodo[1,1'-methylenebis[1,1-diphenylphosphine-κP]]platinum

Chemical Property:

Purity/Quality:

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

Useful:

Technology Process of cis-diiodo[1,1'-methylenebis[1,1-diphenylphosphine-κP]]platinum

There total 8 articles about cis-diiodo[1,1'-methylenebis[1,1-diphenylphosphine-κP]]platinum which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 83.0%

tin(II) iodide + dichloro(bis(diphenylphosphino)methane)platinum(II) (52595-94-5) → cis-diiodo[1,1'-methylenebis[1,1-diphenylphosphine-κP]]platinum (64040-32-0)

Guidance literature:

In tetrahydrofuran; dichloromethane; to soln. of platinum complex in CH2Cl2 was added to soln. of SnI2 in THF, stirred for 4 h; evapd., crystd. from CH2Cl2/hexane;

DOI:10.1002/hlca.201100045

Reference yield: 62.3%

(1,5-cylooctadiene)di-iodoplatinum(II) (12266-72-7) + FeI(CO)(bis(diphenylphosphino)methane-P)(η-C5H5) → [(cyclopentadienyl)Fe(CO)(μ-bis(diphenylphosphino)methane)(μ-I)PtI2] (943527-80-8) + cis-diiodo[1,1'-methylenebis[1,1-diphenylphosphine-κP]]platinum (64040-32-0)

Guidance literature:

In dichloromethane; under Ar; soln. of Fe complex in CH2Cl2 added to suspn. of Pt complex inCH2Cl2; stirred at ambient temp. for 1 h; solvent removed under vac.; purified by column chromy. (silica gel, CH2Cl2); elem. anal.;

DOI:10.1021/om0610750

Reference yield: 57.6%

(1,5-cylooctadiene)di-iodoplatinum(II) (12266-72-7) + [(η5-cyclopentadienyl)Ru(carbonyl)(PPh2CH2PPh2)I] (95419-97-9,95419-94-6) → [(cyclopentadienyl)Ru(CO)(μ-bis(diphenylphosphino)methane)(μ-I)PtI2] (943527-79-5) + cis-diiodo[1,1'-methylenebis[1,1-diphenylphosphine-κP]]platinum (64040-32-0)

Guidance literature:

In dichloromethane; under Ar; soln. of Ru complex in CH2Cl2 added to suspn. of Pt complex inCH2Cl2; stirred at ambient temp. for 1 h; solvent removed under vac.; purified by column chromy. (silica gel, CH2Cl2); elem. anal.;

DOI:10.1021/om0610750

upstream raw materials:

[Pt(oxalate)(bis(diphenylphosphino)methane)]

methyl iodide

(1,5-cylooctadiene)di-iodoplatinum(II)

[(η5-cyclopentadienyl)Ru(carbonyl)(PPh2CH2PPh2)I]

Downstream raw materials:

bis(bis(diphenylphosphino)methane)platinum(II) iodide

PtI₂((C₆H₅)2PCH(CH₃)P(C₆H₅)2)

[PtBr₂(Ph₂PCH(CH₂Ph)PPh₂)]

PtI₂(2,2-bis(diphenylphosphino)propane)