dimethyl(2-methyl-1,3-dithiacyclohexan-2-yl)phenylsilan

Base Information

• Chemical Name: dimethyl(2-methyl-1,3-dithiacyclohexan-2-yl)phenylsilan
• CAS No.: 58309-61-8
• Molecular Formula: C₁₃H₂₀S₂Si
• Molecular Weight: 268.519
• Mol file: 58309-61-8.mol

Synonyms:dimethyl(2-methyl-1,3-dithiacyclohexan-2-yl)phenylsilan

Chemical Property of dimethyl(2-methyl-1,3-dithiacyclohexan-2-yl)phenylsilan

Chemical Property:

Purity/Quality:

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

Useful:

Technology Process of dimethyl(2-methyl-1,3-dithiacyclohexan-2-yl)phenylsilan

There total 3 articles about dimethyl(2-methyl-1,3-dithiacyclohexan-2-yl)phenylsilan which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 62.0%

2-methyl-1,3-dithian (6007-26-7) + phenyldimethylsilyl chloride (768-33-2) → dimethyl(2-methyl-1,3-dithiacyclohexan-2-yl)phenylsilan (58309-61-8)

Guidance literature:

With n-butyllithium; In tetrahydrofuran; hexane; 1.) -30 deg C, 90 min then 0 deg C; 2.) 0 deg C, 3 h then 4 h, room temperature;

DOI:10.1016/0022-328X(86)80492-2

Reference yield:

[1,3]Dithian-2-yl-dimethyl-phenyl-silane (174710-92-0) + methyl iodide (74-88-4) → dimethyl(2-methyl-1,3-dithiacyclohexan-2-yl)phenylsilan (58309-61-8)

Guidance literature:

With phenyllithium; In tetrahydrofuran; diethyl ether; at -78 ℃;

DOI:10.1016/S0040-4020(01)90442-9

Reference yield:

→ dimethyl(2-methyl-1,3-dithiacyclohexan-2-yl)phenylsilan (58309-61-8)

Guidance literature:

2-Methyl-1,3-dithian-Anion, /BRN= 606292/;

DOI:10.1016/S0022-328X(00)86288-9

upstream raw materials:

2-methyl-1,3-dithian

phenyldimethylsilyl chloride

[1,3]Dithian-2-yl-dimethyl-phenyl-silane

methyl iodide

Downstream raw materials:

1-(dimethyl(phenyl)silyl)ethanone

1-Phenylethanol