4-(5'-(7-(5-(4-(10-(tert-butyldimethylsilyloxy)decyloxy)phenyl)thiophen-2-yl)-9,9-dihexyl-9H-fluoren-2-yl)-2,2'-bithiophen-5-yl)pyridine

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Chemical Name:4-(5'-(7-(5-(4-(10-(tert-butyldimethylsilyloxy)decyloxy)phenyl)thiophen-2-yl)-9,9-dihexyl-9H-fluoren-2-yl)-2,2'-bithiophen-5-yl)pyridine
CAS No.:1263559-50-7
Molecular Formula:C₆₄H₈₁NO₂S₃Si
Molecular Weight:1020.64
Hs Code.:

Synonyms:4-(5'-(7-(5-(4-(10-(tert-butyldimethylsilyloxy)decyloxy)phenyl)thiophen-2-yl)-9,9-dihexyl-9H-fluoren-2-yl)-2,2'-bithiophen-5-yl)pyridine

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Chemical Property of 4-(5'-(7-(5-(4-(10-(tert-butyldimethylsilyloxy)decyloxy)phenyl)thiophen-2-yl)-9,9-dihexyl-9H-fluoren-2-yl)-2,2'-bithiophen-5-yl)pyridine

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Technology Process of 4-(5'-(7-(5-(4-(10-(tert-butyldimethylsilyloxy)decyloxy)phenyl)thiophen-2-yl)-9,9-dihexyl-9H-fluoren-2-yl)-2,2'-bithiophen-5-yl)pyridine

There total 9 articles about 4-(5'-(7-(5-(4-(10-(tert-butyldimethylsilyloxy)decyloxy)phenyl)thiophen-2-yl)-9,9-dihexyl-9H-fluoren-2-yl)-2,2'-bithiophen-5-yl)pyridine which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 60.0%

: 897017-73-1
4-(5-tributylstannanyl-thiophen-2-yl)-pyridine

: 1263559-47-2
(10-(4-(5-(7-(5-bromothiophen-2-yl)-9,9-dihexyl-9H-fluoren-2-yl)thiophen-2-yl)phenoxy)decyloxy) (tert-butyl)dimethylsilane

: 1263559-50-7
4-(5'-(7-(5-(4-(10-(tert-butyldimethylsilyloxy)decyloxy)phenyl)thiophen-2-yl)-9,9-dihexyl-9H-fluoren-2-yl)-2,2'-bithiophen-5-yl)pyridine

Guidance literature:: With tetrakis(triphenylphosphine) palladium⁽⁰⁾; potassium carbonate; In ethanol; toluene; for 24h; Reflux; Inert atmosphere;
DOI:10.1016/j.polymer.2010.10.018

Reference yield:

: 2-{4-[10-(tert-butyl-dimethyl-silanyloxy)-decyl]-phenyl}-4,4,5,5-tetramethyl-[1,3,2] dioxaborolane

: 1263559-50-7
4-(5'-(7-(5-(4-(10-(tert-butyldimethylsilyloxy)decyloxy)phenyl)thiophen-2-yl)-9,9-dihexyl-9H-fluoren-2-yl)-2,2'-bithiophen-5-yl)pyridine

Guidance literature:: Multi-step reaction with 2 steps

1: tetrakis(triphenylphosphine) palladium⁽⁰⁾; potassium carbonate / ethanol; toluene / Reflux

2: tetrakis(triphenylphosphine) palladium⁽⁰⁾; potassium carbonate / ethanol; toluene / 24 h / Reflux; Inert atmosphere

With tetrakis(triphenylphosphine) palladium⁽⁰⁾; potassium carbonate; In ethanol; toluene; 1: Suzuki coupling;
DOI:10.1016/j.polymer.2010.10.018

Reference yield:

: 106-41-2
4-bromo-phenol

: 1263559-50-7
4-(5'-(7-(5-(4-(10-(tert-butyldimethylsilyloxy)decyloxy)phenyl)thiophen-2-yl)-9,9-dihexyl-9H-fluoren-2-yl)-2,2'-bithiophen-5-yl)pyridine

Guidance literature:: Multi-step reaction with 5 steps

1.1: potassium carbonate / acetone / 24 h / Reflux

2.1: 1H-imidazole / dichloromethane / 0 - 20 °C / Inert atmosphere

3.1: n-butyllithium / tetrahydrofuran; hexane / -78 - 20 °C / Inert atmosphere

3.2: -78 - 20 °C / Inert atmosphere

4.1: tetrakis(triphenylphosphine) palladium⁽⁰⁾; potassium carbonate / ethanol; toluene / Reflux

5.1: tetrakis(triphenylphosphine) palladium⁽⁰⁾; potassium carbonate / ethanol; toluene / 24 h / Reflux; Inert atmosphere

With 1H-imidazole; tetrakis(triphenylphosphine) palladium⁽⁰⁾; n-butyllithium; potassium carbonate; In tetrahydrofuran; ethanol; hexane; dichloromethane; acetone; toluene; 4.1: Suzuki coupling;
DOI:10.1016/j.polymer.2010.10.018