10-(4-(5-(9,9-dihexyl-7-(5'-(pyridin-4-yl)-2,2'-bithiophen-5-yl)-9H-fluoren-2-yl)thiophen-2-yl)phenoxy)decyl methacrylate

Base Information

Chemical Name:10-(4-(5-(9,9-dihexyl-7-(5'-(pyridin-4-yl)-2,2'-bithiophen-5-yl)-9H-fluoren-2-yl)thiophen-2-yl)phenoxy)decyl methacrylate
CAS No.:1263559-56-3
Molecular Formula:C₆₂H₇₁NO₃S₃
Molecular Weight:974.449
Hs Code.:

Synonyms:10-(4-(5-(9,9-dihexyl-7-(5'-(pyridin-4-yl)-2,2'-bithiophen-5-yl)-9H-fluoren-2-yl)thiophen-2-yl)phenoxy)decyl methacrylate

Suppliers and Price of 10-(4-(5-(9,9-dihexyl-7-(5'-(pyridin-4-yl)-2,2'-bithiophen-5-yl)-9H-fluoren-2-yl)thiophen-2-yl)phenoxy)decyl methacrylate

Supply Marketing:

Business phase:: The product has achieved commercial mass production^*data from LookChem market partment

Manufacturers and distributors:

Manufacture/Brand
Chemicals and raw materials
Packaging
price

Total 0 raw suppliers

Chemical Property of 10-(4-(5-(9,9-dihexyl-7-(5'-(pyridin-4-yl)-2,2'-bithiophen-5-yl)-9H-fluoren-2-yl)thiophen-2-yl)phenoxy)decyl methacrylate

Chemical Property:

Purity/Quality:

Safty Information:

Pictogram(s):
Hazard Codes:

MSDS Files:

Useful:

Technology Process of 10-(4-(5-(9,9-dihexyl-7-(5'-(pyridin-4-yl)-2,2'-bithiophen-5-yl)-9H-fluoren-2-yl)thiophen-2-yl)phenoxy)decyl methacrylate

There total 11 articles about 10-(4-(5-(9,9-dihexyl-7-(5'-(pyridin-4-yl)-2,2'-bithiophen-5-yl)-9H-fluoren-2-yl)thiophen-2-yl)phenoxy)decyl methacrylate which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 81.0%

: 4245-37-8,25719-55-5
vinyl methacrylate

: 1263559-53-0
10-(4-(5-(9,9-dihexyl-7-(5'-(pyridin-4-yl)-2,2'-bithiophen-5-yl)-9H-fluoren-2-yl)thiophen-2-yl)phenoxy)decan-1-ol

: 1263559-56-3
10-(4-(5-(9,9-dihexyl-7-(5'-(pyridin-4-yl)-2,2'-bithiophen-5-yl)-9H-fluoren-2-yl)thiophen-2-yl)phenoxy)decyl methacrylate

Guidance literature:: With 2,6-di-tert-butyl-4-methyl-phenol; 1,3-dichlorotetrabutyldistannoxane; In tetrahydrofuran; at 50 ℃; for 48h; Inert atmosphere;
DOI:10.1016/j.polymer.2010.10.018

Reference yield:

: 2-{4-[10-(tert-butyl-dimethyl-silanyloxy)-decyl]-phenyl}-4,4,5,5-tetramethyl-[1,3,2] dioxaborolane

: 1263559-56-3
10-(4-(5-(9,9-dihexyl-7-(5'-(pyridin-4-yl)-2,2'-bithiophen-5-yl)-9H-fluoren-2-yl)thiophen-2-yl)phenoxy)decyl methacrylate

Guidance literature:: Multi-step reaction with 4 steps

1: tetrakis(triphenylphosphine) palladium⁽⁰⁾; potassium carbonate / ethanol; toluene / Reflux

2: tetrakis(triphenylphosphine) palladium⁽⁰⁾; potassium carbonate / ethanol; toluene / 24 h / Reflux; Inert atmosphere

3: tetrabutyl ammonium fluoride / tetrahydrofuran; hexane / 12.17 h / 20 °C / Cooling with ice

4: 2,6-di-tert-butyl-4-methyl-phenol; 1,3-dichlorotetrabutyldistannoxane / tetrahydrofuran / 48 h / 50 °C / Inert atmosphere

With tetrakis(triphenylphosphine) palladium⁽⁰⁾; 2,6-di-tert-butyl-4-methyl-phenol; tetrabutyl ammonium fluoride; 1,3-dichlorotetrabutyldistannoxane; potassium carbonate; In tetrahydrofuran; ethanol; hexane; toluene; 1: Suzuki coupling;
DOI:10.1016/j.polymer.2010.10.018

Reference yield:

: 1263559-47-2
(10-(4-(5-(7-(5-bromothiophen-2-yl)-9,9-dihexyl-9H-fluoren-2-yl)thiophen-2-yl)phenoxy)decyloxy) (tert-butyl)dimethylsilane

: 1263559-56-3
10-(4-(5-(9,9-dihexyl-7-(5'-(pyridin-4-yl)-2,2'-bithiophen-5-yl)-9H-fluoren-2-yl)thiophen-2-yl)phenoxy)decyl methacrylate

Guidance literature:: Multi-step reaction with 3 steps

1: tetrakis(triphenylphosphine) palladium⁽⁰⁾; potassium carbonate / ethanol; toluene / 24 h / Reflux; Inert atmosphere

2: tetrabutyl ammonium fluoride / tetrahydrofuran; hexane / 12.17 h / 20 °C / Cooling with ice

3: 2,6-di-tert-butyl-4-methyl-phenol; 1,3-dichlorotetrabutyldistannoxane / tetrahydrofuran / 48 h / 50 °C / Inert atmosphere

With tetrakis(triphenylphosphine) palladium⁽⁰⁾; 2,6-di-tert-butyl-4-methyl-phenol; tetrabutyl ammonium fluoride; 1,3-dichlorotetrabutyldistannoxane; potassium carbonate; In tetrahydrofuran; ethanol; hexane; toluene;
DOI:10.1016/j.polymer.2010.10.018