methyl tert-butyl-diphenylsilylcarboxylate

Base Information

• Chemical Name: methyl tert-butyl-diphenylsilylcarboxylate
• CAS No.: 1217974-21-4
• Molecular Formula: C₁₈H₂₂O₂Si
• Molecular Weight: 298.457
• Mol file: 1217974-21-4.mol

Synonyms:methyl tert-butyl-diphenylsilylcarboxylate

Chemical Property of methyl tert-butyl-diphenylsilylcarboxylate

Chemical Property:

Purity/Quality:

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

Useful:

Technology Process of methyl tert-butyl-diphenylsilylcarboxylate

There total 2 articles about methyl tert-butyl-diphenylsilylcarboxylate which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 95.0%

methanol (67-56-1) + tert-butyldiphenylsilanecarboxylic acid (1217974-20-3) → methyl tert-butyl-diphenylsilylcarboxylate (1217974-21-4)

Guidance literature:

With triphenylphosphine; diethylazodicarboxylate; In tetrahydrofuran; toluene; at 20 ℃; for 2h; Inert atmosphere;

DOI:10.1002/anie.200904922

Reference yield: 6.0%

methanol (67-56-1) + tert-butyldiphenylsilanecarboxylic acid (1217974-20-3) → methyl tert-butyl-diphenylsilylcarboxylate (1217974-21-4) + tert-butyl-diphenylsilyl tert-butyl-diphenylsilylcarboxylate (118067-59-7) + tert-butyl(methoxy)diphenylsilane (76358-47-9)

Guidance literature:

With dmap; dicyclohexyl-carbodiimide; In dichloromethane; at 20 ℃; Inert atmosphere;

DOI:10.1002/anie.200904922

upstream raw materials:

methanol

tert-butyldiphenylsilanecarboxylic acid