methyl 3-(2'-bromoethyl)-4-ethylbenzoate

Base Information

Chemical Name:methyl 3-(2'-bromoethyl)-4-ethylbenzoate
CAS No.:165803-97-4
Molecular Formula:C₁₂H₁₅BrO₂
Molecular Weight:271.154
Hs Code.:

Synonyms:methyl 3-(2'-bromoethyl)-4-ethylbenzoate

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Chemical Property of methyl 3-(2'-bromoethyl)-4-ethylbenzoate

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Technology Process of methyl 3-(2'-bromoethyl)-4-ethylbenzoate

There total 9 articles about methyl 3-(2'-bromoethyl)-4-ethylbenzoate which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield:

: 272130-81-1
4-ethyl-3-(2-hydroxy-ethyl)-benzoic acid methyl ester

: 165803-97-4
methyl 3-(2'-bromoethyl)-4-ethylbenzoate

Guidance literature:: With carbon tetrabromide; triphenylphosphine; In dichloromethane; at 0 ℃; for 0.5h;
DOI:10.1021/jm990448e

Reference yield:

: 53596-60-4
methyl 3-allyl-4-hydroxybenzoate

: 165803-97-4
methyl 3-(2'-bromoethyl)-4-ethylbenzoate

Guidance literature:: Multi-step reaction with 7 steps

1.1: O₃ / methanol / 0.08 h / -78 °C

1.2: NaBH₄ / methanol / 14 h / -78 - 20 °C

2.1: 71 percent / imidazole / dimethylformamide / 14 h / 20 °C

3.1: Et₃N / tetrahydrofuran / -78 - 20 °C

4.1: (PPh₃)2PdCl₂; PPh₃; LiCl / dimethylformamide / 14 h / 90 °C

5.1: H₂ / 10percent Pd/C / ethyl acetate / 1 h / 1551.49 Torr

6.1: camphorsulfonic acid / methanol; CH₂Cl₂ / 16 h / 20 °C

7.1: PPh₃; CBr₄ / CH₂Cl₂ / 0.5 h / 0 °C

With 1H-imidazole; bis-triphenylphosphine-palladium(II) chloride; carbon tetrabromide; camphor-10-sulfonic acid; hydrogen; ozone; triethylamine; triphenylphosphine; lithium chloride; 10percent Pd/C; In tetrahydrofuran; methanol; dichloromethane; ethyl acetate; N,N-dimethyl-formamide; 1.1: Ozonolysis / 1.2: Reduction / 2.1: Silylation / 3.1: Triflation / 4.1: Vinylation / 5.1: Catalytic hydrogenation / 6.1: Desilylation / 7.1: Bromination;
DOI:10.1021/jm990448e

Reference yield:

: 99-76-3,156291-94-0
methyl 4-hydroxylbenzoate

: 165803-97-4
methyl 3-(2'-bromoethyl)-4-ethylbenzoate

Guidance literature:: Multi-step reaction with 9 steps

1.1: K₂CO₃ / acetone / 16 h / 0 - 20 °C

2.1: BCl₃ / chlorobenzene / 8 h / 20 °C

3.1: O₃ / methanol / 0.08 h / -78 °C

3.2: NaBH₄ / methanol / 14 h / -78 - 20 °C

4.1: 71 percent / imidazole / dimethylformamide / 14 h / 20 °C

5.1: Et₃N / tetrahydrofuran / -78 - 20 °C

6.1: (PPh₃)2PdCl₂; PPh₃; LiCl / dimethylformamide / 14 h / 90 °C

7.1: H₂ / 10percent Pd/C / ethyl acetate / 1 h / 1551.49 Torr

8.1: camphorsulfonic acid / methanol; CH₂Cl₂ / 16 h / 20 °C

9.1: PPh₃; CBr₄ / CH₂Cl₂ / 0.5 h / 0 °C

With 1H-imidazole; bis-triphenylphosphine-palladium(II) chloride; carbon tetrabromide; camphor-10-sulfonic acid; hydrogen; boron trichloride; potassium carbonate; ozone; triethylamine; triphenylphosphine; lithium chloride; 10percent Pd/C; In tetrahydrofuran; methanol; dichloromethane; ethyl acetate; N,N-dimethyl-formamide; chlorobenzene; acetone; 1.1: Alkylation / 2.1: Rearrangement / 3.1: Ozonolysis / 3.2: Reduction / 4.1: Silylation / 5.1: Triflation / 6.1: Vinylation / 7.1: Catalytic hydrogenation / 8.1: Desilylation / 9.1: Bromination;
DOI:10.1021/jm990448e