53596-60-4

Basic information

• Product Name: methyl 3-allyl-4-hydroxybenzoate
• Synonyms: methyl 3-allyl-4-hydroxybenzoate;3-Allyl-4-hydroxy-benzoic acid methyl ester
• CAS NO: 53596-60-4
• Molecular Formula: C₁₁H₁₂O₃
• Molecular Weight: 192.21118
• Mol File: 53596-60-4.mol
• Article Data: 24

Chemical Properties

• Appearance: /
• CAS DataBase Reference: methyl 3-allyl-4-hydroxybenzoate(CAS DataBase Reference)
• NIST Chemistry Reference: methyl 3-allyl-4-hydroxybenzoate(53596-60-4)
• EPA Substance Registry System: methyl 3-allyl-4-hydroxybenzoate(53596-60-4)

Safety Data

• Hazardous Substances Data: 53596-60-4(Hazardous Substances Data)

Upstream product

• 99-96-7 4-hydroxy-benzoic acid 
• 99-76-3 methyl 4-hydroxylbenzoate 
• 35750-24-4 methyl 4-allyloxybenzoate 
• 95-50-1 1,2-dichloro-benzene 

Downstream Products

• 272130-65-1 3-Allyl-4-methoxy-benzoic acid methyl ester 
• 137421-52-4 methyl 3-(2-propenyl)-4-(2-propenyloxy)benzoate 
• 159590-92-8 α-(4-carbomethoxy-2-n-propylphenoxy)-3,4-methylenedioxyphenylacetic acid 
• 1031393-43-7 3-(4-(4-(1,1,1,3,3,3-hexafluoro-2-hydroxypropan-2-yl)-2-n-propylphenoxy)butyl)-1,5,5-trimethylimidazolidine-2,4-dione 
• 1031401-04-3 1-(4-bromobutoxy)-4-(1,1,1,3,3,3-hexafluoro-2-(methoxymethoxy)propan-2-yl)-2-n-propylbenzene 
• 1031400-93-7 1-(benzyloxy)-4-(1,1,1,3,3,3-hexafluoro-2-(methoxymethoxy)propan-2-yl)-2-n-propylbenzene 
• 150242-78-7 methyl 4-(benzyloxy)-3-n-propylbenzoate 
• 1031393-40-4 3-[4-[4-[1,1,1,3,3,3-hexafluoro-2-(methoxymethyl)oxypropan-2-yl]-2-propylphenyloxy]butyl]-1,5,5-trimethylimidazolidine-2,4-dione 
• 1031393-25-5 4-(1,1,1,3,3,3-hexafluoro-2-(methoxymethoxy)propan-2-yl)-2-n-propylphenol 
• 1031400-91-5 2-(4-(benzyloxy)-3-n-propylphenyl)-1,1,1,3,3,3-hexafluoropropan-2-ol 

Relevant articles and documents

Investigating the microwave-accelerated Claisen rearrangement of allyl aryl ethers: Scope of the catalysts, solvents, temperatures, and substrates

The microwave-accelerated Claisen rearrangement of allyl aryl ethers was investigated, in order to gain insight into the scope of the catalysts, solvents, temperatures, and substrates. Among the catalysts examined, phosphomolybdic acid (PMA) was found to greatly accelerate the reaction in NMP, at temperatures ranging from 220 to 300 °C. This method was found to be useful for preparing several intermediates previously reported in the literature using precious metal catalysts such as Au(I), Ag(I), and Pt(II). Additionally, substrates bearing bromo and nitro groups on the aryl portion required careful tailoring of the reaction conditions to avoid complex product profiles.

Designed Spiroketal Protein Modulation

Spiroketals are structural motifs found in many biologically active natural products, which has stimulated considerable efforts toward their synthesis and interest in their use as drug lead compounds. Despite this, the use of spiroketals, and especially b

An atom-economical and stereoselective domino synthesis of functionalised dienes

Open sesame: A direct synthesis of functionalised and stereodefined dienes, relying on a domino allylic alkylation/electrocyclic ring-opening sequence, is reported. This method allows concise access to doubly vinylogous esters. A further systematic study