(octaethylporphyrinato)rhodium(III) iodide

Base Information

Chemical Name:(octaethylporphyrinato)rhodium(III) iodide
CAS No.:69509-36-0
Molecular Formula:C₃₆H₄₄IN₄Rh
Molecular Weight:762.582
Hs Code.:

Synonyms:(octaethylporphyrinato)rhodium(III) iodide

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Business phase:: The product has achieved commercial mass production^*data from LookChem market partment

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Chemical Property of (octaethylporphyrinato)rhodium(III) iodide

Chemical Property:

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Technology Process of (octaethylporphyrinato)rhodium(III) iodide

There total 1 articles about (octaethylporphyrinato)rhodium(III) iodide which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield:

: 57497-95-7
(octaethylporphyrinato)phenylrhodium(III)

: 591-50-4
iodobenzene

: 69509-36-0
(octaethylporphyrinato)rhodium(III) iodide

Guidance literature:: With iodine; In dichloromethane; benzene; soln. containing iodine was stirred at room temp. under N2 for 3 d; soln. was washed with aq. Na2S2O4, organic layer was dried (Na2SO4), chromd. on silica gel;
DOI:10.1021/om00132a030

Reference yield:

: 69509-36-0
(2,3,7,8,12,13,17,18=octaethylporphyrinato)RhI

: 618-32-6
Benzoyl bromide

: 172226-09-4
Rh(octaethylporphyrinato)C(O)C₆H₅

Guidance literature:: With sodium hydroxide; sodium tetrahydroborate; In ethanol; N2-atmosphere; stirring Rh-complex with NaBH4/NaOH (40°C, 2 h), addn. of slight excess org. bromide at room temp., stirring in dark for 3h; shaking with C6H6/water mixt., washing org. layer (water), drying (Na2SO4), concn., chromy. (Al2O3, C6H6), evapn. (vac.);
DOI:10.1016/0022-328X(95)05569-B

Reference yield:

: 69509-36-0
(2,3,7,8,12,13,17,18=octaethylporphyrinato)RhI

: 70-11-1
α-bromoacetophenone

: 172226-07-2
Rh(octaethylporphyrinato)CH₂C(O)C₆H₅

Guidance literature:: With sodium hydroxide; sodium tetrahydroborate; In ethanol; N2-atmosphere; stirring Rh-complex with NaBH4/NaOH (40°C, 2 h), addn. of slight excess org. bromide at room temp., stirring in dark for 3h; shaking with C6H6/water mixt., washing org. layer (water), drying (Na2SO4), concn., chromy. (Al2O3, C6H6), evapn. (vac.);
DOI:10.1016/0022-328X(95)05569-B