RuH(CH₃COO)[(S)-binap]P(C₆H₅)

Base Information

• Chemical Name: RuH(CH₃COO)[(S)-binap]P(C₆H₅)
• CAS No.: 440634-48-0
• Molecular Formula: C₆₄H₅₁O₂P₃Ru
• Molecular Weight: 1046.1
• Mol file: 440634-48-0.mol

Synonyms:RuH(CH₃COO)[(S)-binap]P(C₆H₅)

Chemical Property of RuH(CH₃COO)[(S)-binap]P(C₆H₅)

Chemical Property:

Purity/Quality:

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Technology Process of RuH(CH₃COO)[(S)-binap]P(C₆H₅)

There total 1 articles about RuH(CH₃COO)[(S)-binap]P(C₆H₅) which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 70.0%

Ru(OCOCH3)2{(S)-2,2'-bis(diphenylphosphino)-1,1'-dinaphthyl)} (114818-52-9,104713-03-3,261948-85-0,325146-81-4,104621-48-9) + hydrogen (1333-74-0) + triphenylphosphine (603-35-0) → RuH(CH3COO)[(S)-binap]P(C6H5) (440634-48-0)

Guidance literature:

In methanol; soln. exposed to 1.2 atm of H2 at 25 °C for 4 h, at 4 °C for 24 h; supernatant removed, washed with CH3OH, dried in vac., dissolved in toluene, hexane placed on toluene soln, kept at 3 °C for 7 d, mother liquor removed, washed with hexane, dried in vac.; elem anal.;

DOI:10.1021/ja010982n

upstream raw materials:

Ru(OCOCH₃)2{(S)-2,2'-bis(diphenylphosphino)-1,1'-dinaphthyl)}

hydrogen

triphenylphosphine

Refernces