tricarbonyldi(triphenylphosphine)cobalt⁽¹⁺⁾ tetracarbonylcobaltate^(1-)

Base Information

Chemical Name:tricarbonyldi(triphenylphosphine)cobalt⁽¹⁺⁾ tetracarbonylcobaltate^(1-)
CAS No.:14243-08-4
Molecular Formula:C₄CoO₄*C₃₉H₃₀CoO₃P₂
Molecular Weight:838.641
Hs Code.:

tricarbonyldi(triphenylphosphine)cobalt<sup>(1+)</sup> tetracarbonylcobaltate<sup>(1-)</sup>

Synonyms:tricarbonyldi(triphenylphosphine)cobalt⁽¹⁺⁾ tetracarbonylcobaltate^(1-)

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Business phase:: The product has achieved commercial mass production^*data from LookChem market partment

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Chemical Property of tricarbonyldi(triphenylphosphine)cobalt⁽¹⁺⁾ tetracarbonylcobaltate^(1-)

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Technology Process of tricarbonyldi(triphenylphosphine)cobalt⁽¹⁺⁾ tetracarbonylcobaltate^(1-)

There total 10 articles about tricarbonyldi(triphenylphosphine)cobalt⁽¹⁺⁾ tetracarbonylcobaltate^(1-) which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 96.0%

: [μ2-(ethoxycarbonyl(methylene))-μ2-(carbonyl)-bis(triphenylphosphane-dicarbonyl-cobalt) (Co-Co)]

: 201230-82-2
carbon monoxide

: 14243-08-4
tricarbonyldi(triphenylphosphine)cobalt⁽¹⁺⁾ tetracarbonylcobaltate^(1-)

: 105-53-3
diethyl malonate

Guidance literature:: With ethanol; In dichloromethane; High Pressure; soln. of cobalt complex and anhyd. ethanol pressurized with CO in autoclave at 25°C and 50 bar for 24 h; IR;
DOI:10.1016/j.molcata.2005.04.027

Reference yield: 78.0%

: 15226-74-1,61091-28-9,61117-58-6
dicobalt octacarbonyl

: 603-35-0
triphenylphosphine

: 14243-08-4
tricarbonyldi(triphenylphosphine)cobalt⁽¹⁺⁾ tetracarbonylcobaltate^(1-)

: 10170-27-1,190336-13-1
hexacarbonyldi(triphenylphosphine)dicobalt(O)

Guidance literature:: In tetrahydrofuran; (N2); standard Schlenk technique; PPh3 (8 equiv.) was added to soln. of Co complex in THF at ambient temp.; soln. was stirred for 20 min; cooled to 0°C; filtered via cannula under N2; hexane added to filtrate; filtered; washed (hexane); dried (vac.); elem. anal.;
DOI:10.1039/b303208f

Reference yield:

: 15226-74-1,61091-28-9,61117-58-6
dicobalt octacarbonyl

: 14243-08-4
tricarbonyldi(triphenylphosphine)cobalt⁽¹⁺⁾ tetracarbonylcobaltate^(1-)

Guidance literature:: With oxygen; triphenylphosphine; In hexane; byproducts: CO; (N2); a soln. of Co2(CO)8 (saturated with O2 and without O2) treated with PPh3 from 0 to 15°C; elem. anal.; Kinetics;
DOI:10.1021/ja00540a012