4-(pyrrolidin-1-ylazo)-benzoic acid ethyl ester

Base Information

Chemical Name:4-(pyrrolidin-1-ylazo)-benzoic acid ethyl ester
CAS No.:1425947-05-2
Molecular Formula:C₁₃H₁₇N₃O₂
Molecular Weight:247.297
Hs Code.:

Synonyms:4-(pyrrolidin-1-ylazo)-benzoic acid ethyl ester

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Chemical Property of 4-(pyrrolidin-1-ylazo)-benzoic acid ethyl ester

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Technology Process of 4-(pyrrolidin-1-ylazo)-benzoic acid ethyl ester

There total 1 articles about 4-(pyrrolidin-1-ylazo)-benzoic acid ethyl ester which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield:

: 123-75-1
pyrrolidine

: 94-09-7
p-aminoethylbenzoate

: 1425947-05-2
4-(pyrrolidin-1-ylazo)-benzoic acid ethyl ester

Guidance literature:: p-aminoethylbenzoate; With hydrogenchloride; sodium nitrite; In water; for 0.166667h; Cooling with ice;

pyrrolidine; In water; for 0.5h; Cooling with ice;
DOI:10.1039/c4cc08367a

Reference yield: 72.0%

: 1425947-05-2
4-(pyrrolidin-1-ylazo)-benzoic acid ethyl ester

: 100-44-7
benzyl chloride

: 58324-80-4
ethyl 4-(benzylthio)benzoate

Guidance literature:: benzyl chloride; With [2,2]bipyridinyl; copper(ll) sulfate pentahydrate; Sodium thiosulfate pentahydrate; In water; at 80 ℃; for 2h; Schlenk technique;

4-(pyrrolidin-1-ylazo)-benzoic acid ethyl ester; With boron trifluoride diethyl etherate; In water; at 20 ℃; for 12h; Schlenk technique;
DOI:10.1039/c4cc08367a

Reference yield:

: 1425947-05-2
4-(pyrrolidin-1-ylazo)-benzoic acid ethyl ester

: 94-09-7
p-aminoethylbenzoate

Guidance literature:: Multi-step reaction with 2 steps

1: sodium azide; boron trifluoride diethyl etherate; trifluoroacetic acid / dichloromethane / 0.5 h / 0 - 20 °C

2: tris(triphenylphosphine)ruthenium(II) chloride / isopropyl alcohol / 48 h / 110 °C / Schlenk technique; Inert atmosphere

With tris(triphenylphosphine)ruthenium(II) chloride; sodium azide; boron trifluoride diethyl etherate; trifluoroacetic acid; In dichloromethane; isopropyl alcohol;
DOI:10.1021/ol400223d