(2R)-(-)-Glycidyl 4-nitrobenzoate

Base Information

Chemical Name:(2R)-(-)-Glycidyl 4-nitrobenzoate
CAS No.:106268-95-5
Molecular Formula:C10H9 N O5
Molecular Weight:223.185
Hs Code.:2916399090
European Community (EC) Number:622-897-3
UNII:F9VQW99PJV
Nikkaji Number:J471.951D
Mol file:106268-95-5.mol

Synonyms:106268-95-5;(2R)-(-)-Glycidyl 4-nitrobenzoate;(R)-(-)-Glycidyl-4-nitrobenzoate;4-Nitrobenzoic acid (R)-oxiranylmethyl ester;[(2R)-oxiran-2-yl]methyl 4-nitrobenzoate;F9VQW99PJV;((2R)-OXIRAN-2-YL)METHYL 4-NITROBENZOATE;Glycidyl 4-nitrobenzoate, (R)-;R(-)-GLYCIDYL 4-NITROBENZOATE;10-Phenothiazinepropiocicacid;SCHEMBL3035603;AKOS025311488;(R)-oxiran-2-ylmethyl 4-nitrobenzoate;GLYCIDYL 4-NITROBENZOATE, (-)-;(2R)-(-)-Glycidyl 4-nitrobenzoate, 98%;(R)-(4-NITROBENZOYLOXYMETHYL)OXIRANE;J-001559;2-OXIRANEMETHANOL, 2-(4-NITROBENZOATE), (2R)-

Suppliers and Price of (2R)-(-)-Glycidyl 4-nitrobenzoate

Supply Marketing:

Business phase:: The product has achieved commercial mass production^*data from LookChem market partment

Manufacturers and distributors:

Manufacture/Brand
Chemicals and raw materials
Packaging
price

Sigma-Aldrich
(2R)-(?)-Glycidyl 4-nitrobenzoate 98%
1g
$ 82.30

American Custom Chemicals Corporation
(R)-(-)-GLYCIDYL-4-NITROBENZOATE 95.00%
1G
$ 680.11

AHH
(R)-(-)-Glycidyl-4-nitrobenzoate 98%
10g
$ 328.00

Total 7 raw suppliers

Chemical Property of (2R)-(-)-Glycidyl 4-nitrobenzoate

Chemical Property:

Vapor Pressure:4.45E-06mmHg at 25°C
Melting Point:60-62 °C
Boiling Point:383.3°Cat760mmHg
Flash Point:187.5°C
PSA：84.65000
Density:1.399g/cm³
LogP:1.67360
Storage Temp.:2-8°C
XLogP3:1.7
Hydrogen Bond Donor Count:0
Hydrogen Bond Acceptor Count:5
Rotatable Bond Count:4
Exact Mass:223.04807239
Heavy Atom Count:16
Complexity:279

Purity/Quality:

99% ^*data from raw suppliers

(2R)-(?)-Glycidyl 4-nitrobenzoate 98% ^*data from reagent suppliers

Safty Information:

Pictogram(s):
Hazard Codes:Xi
Statements: 36/37/38
Safety Statements: 26-36

MSDS Files:: SDS file from LookChem

Useful:

Canonical SMILES:C1C(O1)COC(=O)C2=CC=C(C=C2)[N+](=O)[O-]
Isomeric SMILES:C1[C@@H](O1)COC(=O)C2=CC=C(C=C2)[N+](=O)[O-]
Uses (2R)-(?)-Glycidyl 4-nitrobenzoate can be used as a starting material in the total synthesis of leukotriene B4.

Technology Process of (2R)-(-)-Glycidyl 4-nitrobenzoate

There total 8 articles about (2R)-(-)-Glycidyl 4-nitrobenzoate which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield:

: 13318-11-1
2-((4-nitrobenzoyloxy)methyl)oxirane

: 106268-95-5
(R)-glycidyl 4-nitrobenzoate

: 60456-23-7
(S)-oxiranemethanol

Guidance literature:: With lipasePS-C; In tetrahydrofuran; water; for 13h; Ambient temperature;
DOI:10.1080/00397919908086413

Reference yield:

: 3847-57-2
sodium 4-nitrobenzoate

: 106-89-8,24969-06-0,13403-37-7
epichlorohydrin

: 106268-95-5
(R)-glycidyl 4-nitrobenzoate

: 60456-23-7
(S)-oxiranemethanol

: 115459-65-9
oxiran-2-ylmethyl-4-nitrobenzoate

Guidance literature:: With 15-crown-5; lipasePS-C; Multistep reaction. Title compound not separated from byproducts; 1.) CH₃CN, 12 h, room temp., 2.) THF, water, 13 h, room temp.;
DOI:10.1080/00397919908086413

Reference yield:

: 3847-57-2
sodium 4-nitrobenzoate

: 106268-95-5
(R)-glycidyl 4-nitrobenzoate

Guidance literature:: Multi-step reaction with 2 steps

1: 92 percent / 15-crown-5 / acetonitrile / 12 h / Ambient temperature

2: lipasePS-C / tetrahydrofuran; H₂O / 13 h / Ambient temperature

With 15-crown-5; lipasePS-C; In tetrahydrofuran; water; acetonitrile;
DOI:10.1080/00397919908086413