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Technology Process of {IrCl(CO)(P(C6H5)2CH2(N(CH2)2O(CH2)2O(CH2)2N(CH2P(C6H5)2)(CH2)2O(CH2)2O(CH2)2))}

{IrCl(CO)(P(C6H5)2CH2(N(CH2)2O(CH2)2O(CH2)2N(CH2P(C6H5)2)(CH2)2O(CH2)2O(CH2)2))}

Base Information
  • Chemical Name:{IrCl(CO)(P(C6H5)2CH2(N(CH2)2O(CH2)2O(CH2)2N(CH2P(C6H5)2)(CH2)2O(CH2)2O(CH2)2))}
  • CAS No.:132673-23-5
  • Molecular Formula:C39H48ClIrN2O5P2
  • Molecular Weight:914.441
  • Hs Code.:
{IrCl(CO)(P(C<sub>6</sub>H<sub>5</sub>)2CH<sub>2</sub>(N(CH<sub>2</sub>)2O(CH<sub>2</sub>)2O(CH<sub>2</sub>)2N(CH<sub>2</sub>P(C<sub>6</sub>H<sub>5</sub>)2)(CH<sub>2</sub>)2O(CH<sub>2</sub>)2O(CH<sub>2</sub>)2))}

Synonyms:{IrCl(CO)(P(C6H5)2CH2(N(CH2)2O(CH2)2O(CH2)2N(CH2P(C6H5)2)(CH2)2O(CH2)2O(CH2)2))}

Suppliers and Price of {IrCl(CO)(P(C6H5)2CH2(N(CH2)2O(CH2)2O(CH2)2N(CH2P(C6H5)2)(CH2)2O(CH2)2O(CH2)2))}
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Chemical Property of {IrCl(CO)(P(C6H5)2CH2(N(CH2)2O(CH2)2O(CH2)2N(CH2P(C6H5)2)(CH2)2O(CH2)2O(CH2)2))}
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Technology Process of {IrCl(CO)(P(C6H5)2CH2(N(CH2)2O(CH2)2O(CH2)2N(CH2P(C6H5)2)(CH2)2O(CH2)2O(CH2)2))}

There total 1 articles about {IrCl(CO)(P(C6H5)2CH2(N(CH2)2O(CH2)2O(CH2)2N(CH2P(C6H5)2)(CH2)2O(CH2)2O(CH2)2))} which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 77.0%

chlorodicarbonyl(p-toluidine)iridium
14243-22-2,59952-74-8

chlorodicarbonyl(p-toluidine)iridium

crown-P<sub>2</sub>
128496-90-2

crown-P2

{IrCl(CO)(P(C<sub>6</sub>H<sub>5</sub>)2CH<sub>2</sub>(N(CH<sub>2</sub>)2O(CH<sub>2</sub>)2O(CH<sub>2</sub>)2N(CH<sub>2</sub>P(C<sub>6</sub>H<sub>5</sub>)2)(CH<sub>2</sub>)2O(CH<sub>2</sub>)2O(CH<sub>2</sub>)2))}
132673-23-5

{IrCl(CO)(P(C6H5)2CH2(N(CH2)2O(CH2)2O(CH2)2N(CH2P(C6H5)2)(CH2)2O(CH2)2O(CH2)2))}

Guidance literature:
In toluene; slow addn. of the Ir compd. in toluene to the ligand in toluene over 1 h and stirring for 1 h; evapn. and addn. of Et2O; elem. anal.;
DOI:10.1021/ja00008a030

Reference yield: 73.0%

{IrCl(CO)(P(C<sub>6</sub>H<sub>5</sub>)2CH<sub>2</sub>(N(CH<sub>2</sub>)2O(CH<sub>2</sub>)2O(CH<sub>2</sub>)2N(CH<sub>2</sub>P(C<sub>6</sub>H<sub>5</sub>)2)(CH<sub>2</sub>)2O(CH<sub>2</sub>)2O(CH<sub>2</sub>)2))}
132673-23-5

{IrCl(CO)(P(C6H5)2CH2(N(CH2)2O(CH2)2O(CH2)2N(CH2P(C6H5)2)(CH2)2O(CH2)2O(CH2)2))}

{IrI(CO)K(P(C<sub>6</sub>H<sub>5</sub>)2CH<sub>2</sub>(N((CH<sub>2</sub>)2O)2(CH<sub>2</sub>)2N(CH<sub>2</sub>P(C<sub>6</sub>H<sub>5</sub>)2)((CH<sub>2</sub>)2O)2(CH<sub>2</sub>)2))}<sup>(1+)</sup>*I<sup>(1-)</sup>={C<sub>39</sub>H<sub>48</sub>IIrKN<sub>2</sub>O<sub>5</sub>P<sub>2</sub>}I
135107-61-8

{IrI(CO)K(P(C6H5)2CH2(N((CH2)2O)2(CH2)2N(CH2P(C6H5)2)((CH2)2O)2(CH2)2))}(1+)*I(1-)={C39H48IIrKN2O5P2}I

Guidance literature:
With KI; In methanol; dichloromethane; (N2 atmosphere); a 5-fold excess of KI dissolved in MeOH is added to a soln. of Ir-complex in CH2Cl2, soln. is stirred for 1 h; solvents are removed by rotary evapn., residue is dissolved in CH2Cl2, filtn., dropwise addn. of Et2O, pptn., ppt. is collected by filtn., washed with Et2O, dried in vac., elem. anal.;

Reference yield: 73.0%

{IrCl(CO)(P(C<sub>6</sub>H<sub>5</sub>)2CH<sub>2</sub>(N(CH<sub>2</sub>)2O(CH<sub>2</sub>)2O(CH<sub>2</sub>)2N(CH<sub>2</sub>P(C<sub>6</sub>H<sub>5</sub>)2)(CH<sub>2</sub>)2O(CH<sub>2</sub>)2O(CH<sub>2</sub>)2))}
132673-23-5

{IrCl(CO)(P(C6H5)2CH2(N(CH2)2O(CH2)2O(CH2)2N(CH2P(C6H5)2)(CH2)2O(CH2)2O(CH2)2))}

sodium tetraphenyl borate
143-66-8

sodium tetraphenyl borate

lead(II) acetate trihydrate
6080-56-4

lead(II) acetate trihydrate

{IrCl(CO)Pb(P(C<sub>6</sub>H<sub>5</sub>)2CH<sub>2</sub>(N((CH<sub>2</sub>)2O)2(CH<sub>2</sub>)2N(CH<sub>2</sub>P(C<sub>6</sub>H<sub>5</sub>)2)((CH<sub>2</sub>)2O)2(CH<sub>2</sub>)2))}<sup>(2+)</sup>*2B(C<sub>6</sub>H<sub>5</sub>)4<sup>(1-)</sup>
135107-50-5

{IrCl(CO)Pb(P(C6H5)2CH2(N((CH2)2O)2(CH2)2N(CH2P(C6H5)2)((CH2)2O)2(CH2)2))}(2+)*2B(C6H5)4(1-)

Guidance literature:
In methanol; dichloromethane; (N2 atmosphere); a soln. of lead(II) acetate trihydrate in MeOH is added to a stirred soln. of Ir-complex in CH2Cl2, soln. brightened in hue after 30 min of stirring, a 6-fold excess of NaBPh4 in MeOH is added, mixt. is stirred for 30 min; addn. of MeOH caused a pale yellow solid to precipitate, ppt. is collected by filtn., washed with MeOH and Et2O, dried in vac., elem. anal.;
upstream raw materials:

chlorodicarbonyl(p-toluidine)iridium

crown-P2

Downstream raw materials:

{IrCl(CO)SnCl(P(C6H5)2CH2(N(CH2)2O(CH2)2O(CH2)2N(CH2P(C6H5)2)(CH2)2O(CH2)2O(CH2)2))}(1+)*SnCl3(1-)*CHCl3

{IrCl(CO)K(P(C6H5)2CH2(N((CH2)2O)2(CH2)2N(CH2P(C6H5)2)((CH2)2O)2(CH2)2))}(1+)*PF6(1-)*0.5CH2Cl2

{IrCl(CO)Pb(P(C6H5)2CH2(N((CH2)2O)2(CH2)2N(CH2P(C6H5)2)((CH2)2O)2(CH2)2))}(2+)*2B(C6H5)4(1-)

{IrCl(CO)Na(P(C6H5)2CH2(N((CH2)2O)2(CH2)2N(CH2P(C6H5)2)((CH2)2O)2(CH2)2))}(1+)*B(C6H5)4(1-)

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