Palladium(II), tetraammine-, tetrachloropalladate(II)

Base Information

• Chemical Name: Palladium(II), tetraammine-, tetrachloropalladate(II)
• CAS No.: 13820-44-5
• Molecular Formula: H12Cl4N4Pd2
• Molecular Weight: 422.774
• Mol file: 13820-44-5.mol

Synonyms:EINECS 237-500-5;NSC 212525;Palladium(II), tetraammine-, tetrachloropalladate(II)

Chemical Property of Palladium(II), tetraammine-, tetrachloropalladate(II)

Chemical Property:

• Melting Point: 192 °C (dec.)(lit.)
• PSA: 12.96000
• Density: 2.489 g/mL at 25 °C(lit.)
• LogP: 4.05360
• Hydrogen Bond Donor Count: 4
• Hydrogen Bond Acceptor Count: 8
• Rotatable Bond Count: 0
• Exact Mass: 423.78603
• Heavy Atom Count: 10
• Complexity: 0

Purity/Quality:

98%,99%, ^*data from raw suppliers

Tetraammine palladium(II) tetrachloropalladate(II), 99% ^*data from reagent suppliers

Safty Information:

• Pictogram(s): Xi
• Hazard Codes: Xi
• Statements: 36/37/38
• Safety Statements: 26-36

MSDS Files:

SDS file from LookChem

Useful:

• Canonical SMILES: N.N.N.N.[Cl-].[Cl-].[Cl-].[Cl-].[Pd+2].[Pd+2]

Technology Process of Palladium(II), tetraammine-, tetrachloropalladate(II)

There total 20 articles about Palladium(II), tetraammine-, tetrachloropalladate(II) which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield:

palladium hydroxide + ammonium chloride → trans-diamminedichloride palladium(II) (13782-33-7,14323-43-4,15684-18-1) + Vauquelin's salt (13820-44-5)

Guidance literature:

In water; heating (30°C, 1 h);

Reference yield:

palladium dichloride → Vauquelin's salt (13820-44-5)

Guidance literature:

With ammonia; In water; on addn. of small amt. of NH3-soln., forming of (Pd(NH3)4)(PdCl4), which is dissolved in excess of pptg. reagent to a colorless liquid;;

Reference yield:

ammonia (7664-41-7) + palladium dichloride → Vauquelin's salt (13820-44-5)

Guidance literature:

In not given; on treating of a PdCl2 soln. with NH3 soln. in excess, first forming of a light cinnamon brown ppte., which is getting peach blossom red on further addn. of NH3;; not isolated;;

upstream raw materials:

tetramminepalladium(II) chloride

potassium tetrachloropalladate(II)

tetraamminepalladium(II)hexachloropalladate(IV)

tetraamminepalladium(II)⁽²⁺⁾

Downstream raw materials:

tetramminepalladium(II) chloride

cis-dichlorodiamminepalladium(II)

trans dichloro diammine palladium (II)

tetrachloro diammine palladium (IV)

Refernces