Diamminedichloropalladium

Base Information

• Chemical Name: Diamminedichloropalladium
• CAS No.: 15684-18-1
• Molecular Formula: Cl₂H₆N₂Pd
• Molecular Weight: 211.387
• European Community (EC) Number: 238-269-3,239-768-9,237-437-3
• Wikidata: Q4162554
• Mol file: 15684-18-1.mol

Synonyms:13782-33-7;Diamminedichloropalladium;trans-Diamminedichloropalladium(II);Diammine dichloropalladium;azane;dichloropalladium;trans-Diamminedichloropalladium;trans-Diammine dichloropalladium;MFCD00011621;trans-Dichlorodiammine palladium (II);trans-Dichlorodiammine palladium(II);Cl2H6N2Pd;Cl2-H6-N2-Pd;Diammine dichloropalladium(II);Palladium(II) diammine dichloride;AMY39310;AKOS015903706;Palladium(II), dichlorodiammine-, trans-;CS-0080662;trans-Diamminedichloropalladium(II), Premion;trans-Diamminedichloropalladium(II), 99.998%;Palladium, diamminedichloro-, (SP-4-1)- (9CI);J-520226;Q4162554

Chemical Property of Diamminedichloropalladium

Chemical Property:

• PSA: 52.04000
• LogP: 1.59840
• Hydrogen Bond Donor Count: 2
• Hydrogen Bond Acceptor Count: 2
• Rotatable Bond Count: 0
• Exact Mass: 209.89428
• Heavy Atom Count: 5
• Complexity: 2.8

Purity/Quality:

99% ^*data from raw suppliers

Safty Information:

• Pictogram(s): R23/24/25:; R36/37/38:
• Hazard Codes: T:Toxic
• Statements: R23/24/25:; R36/37/38:
• Safety Statements: S22:; S26:; S36/37/39:; S45:

MSDS Files:

SDS file from LookChem

Useful:

• Canonical SMILES: N.N.Cl[Pd]Cl

Technology Process of Diamminedichloropalladium

There total 54 articles about Diamminedichloropalladium which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 100.0%

ammonium tetrachloropalladate(II) → trans-diamminedichloride palladium(II) (13782-33-7,14323-43-4,15684-18-1)

Guidance literature:

In neat (no solvent); byproducts: HCl; isothermal decompn. at 216°C; elem. anal.;

Reference yield: 96.0%

ammonia (7664-41-7) + palladium dichloride → diamminedichloropalladium(II) (14323-43-4,15684-18-1,13782-33-7)

Guidance literature:

In hydrogenchloride; PdCl2 was dissolved in 0.2 M HCl, 25 % aq. NH3 was added at 50 °C, stirring for 2 h; soln. was ice-cooled, concd. HCl was added, solid was filtered, washed several times with water (ice-cooled), dried;

Reference yield: 90.0%

chloroauric acid + tetraamminepalladium(II) nitrate → diamminedichloropalladium(II) (14323-43-4,15684-18-1,13782-33-7) + tetraamminepalladium(II) tetrachloroaurate (III)

Guidance literature:

In water; HAuCl4 added to satd. aq. soln. of Pd(NH3)4(NO3)2; ppt. filtered off (vac.); washed (min. amt. of H2O, EtOH); dried (air); elem. anal.;

DOI:10.1134/S0036023607030138

upstream raw materials:

hydrogenchloride

tetramminepalladium(II) chloride

cis-dichlorodiamminepalladium(II)

trans difluoro diammine palladium (II)

Downstream raw materials:

palladium

tetrachloro diammine palladium (IV)

{Pd(NH₃)2(NO₃)2}

trans diiodo diammine palladium (II)

Refernces

• 1、 Mitkina, Tatiana V.,Naumov, Dmitriy Yu.,Gerasko, Olga A.,Fedin, Vladimir P.. "Crystal structure and chemical oxidation of the palladium(II) cyclam complex within the cavity of cucurbit[8]uril". . p. 4387 - 4391. Retrieved 2011/02/28.
• 2、 Kluefers, Peter. "Polyol metal complexes. 38. Diammine dihydroxo palladium(II), a new agent for carbohydrate coordination". . p. 2042 - 2044. Retrieved 2008/10/08.