pyrrole-2-(N-o-bromophenyl)aldimine

Base Information

• Chemical Name: pyrrole-2-(N-o-bromophenyl)aldimine
• CAS No.: 145627-43-6
• Molecular Formula: C₁₁H₉BrN₂
• Molecular Weight: 249.11
• Mol file: 145627-43-6.mol

Synonyms:pyrrole-2-(N-o-bromophenyl)aldimine

Chemical Property of pyrrole-2-(N-o-bromophenyl)aldimine

Chemical Property:

Purity/Quality:

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MSDS Files:

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Technology Process of pyrrole-2-(N-o-bromophenyl)aldimine

There total 1 articles about pyrrole-2-(N-o-bromophenyl)aldimine which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 54.0%

2-pyrrole aldehyde (1003-29-8,254729-95-8) + 2-bromoaniline (615-36-1) → pyrrole-2-(N-o-bromophenyl)aldimine (145627-43-6)

Guidance literature:

With toluene-4-sulfonic acid; In toluene; at 130 ℃; for 48h;

DOI:10.1039/d0dt01845g

Reference yield: 53.0%

pyrrole-2-(N-o-bromophenyl)aldimine (145627-43-6) + triphenylborane (960-71-4) → C23H18BBrN2

Guidance literature:

In toluene; Inert atmosphere; Reflux;

DOI:10.1039/d0dt01845g

Reference yield: 10.0%

pyrrole-2-(N-o-bromophenyl)aldimine (145627-43-6) + tetraethylammonium tetrabromoniccolate(II) → nickel(II)(N-o-Br-phenyl-pyrrole-2-aldimine)2 (146108-43-2)

Guidance literature:

With potassium t-butoxide; In tetrahydrofuran; separate dissolution of ligand and potassium t-butoxide in anhyd. THF, mixing, addn. of solid (NEt4)2NiBr4, stirring for 48 h at room temp.; filtn., reducing filtrate in volume to a dark oil, addn. of a few drops of ethanol, crystn. after 6 h stirring, recrystn. from n-hexane/methylene chloride, elem. anal.;

DOI:10.1016/S0277-5387(00)80241-7

upstream raw materials:

2-pyrrole aldehyde

2-bromoaniline

Downstream raw materials:

copper(II)(N-o-Br-phenylpyrrole-2-aldiminate)2

nickel(II)(N-o-Br-phenyl-pyrrole-2-aldimine)2