(S)-2-[(S)-4-(tert-Butyl-diphenyl-silanyloxy)-2-triethylsilanyloxy-butyl]-oxirane

Base Information

Chemical Name:(S)-2-[(S)-4-(tert-Butyl-diphenyl-silanyloxy)-2-triethylsilanyloxy-butyl]-oxirane
CAS No.:201868-03-3
Molecular Formula:C₂₈H₄₄O₃Si₂
Molecular Weight:484.827
Hs Code.:

Synonyms:(S)-2-[(S)-4-(tert-Butyl-diphenyl-silanyloxy)-2-triethylsilanyloxy-butyl]-oxirane

Suppliers and Price of (S)-2-[(S)-4-(tert-Butyl-diphenyl-silanyloxy)-2-triethylsilanyloxy-butyl]-oxirane

Supply Marketing:

Business phase:: The product has achieved commercial mass production^*data from LookChem market partment

Manufacturers and distributors:

Manufacture/Brand
Chemicals and raw materials
Packaging
price

Total 0 raw suppliers

Chemical Property of (S)-2-[(S)-4-(tert-Butyl-diphenyl-silanyloxy)-2-triethylsilanyloxy-butyl]-oxirane

Chemical Property:

Purity/Quality:

Safty Information:

Pictogram(s):
Hazard Codes:

MSDS Files:

Useful:

Technology Process of (S)-2-[(S)-4-(tert-Butyl-diphenyl-silanyloxy)-2-triethylsilanyloxy-butyl]-oxirane

There total 2 articles about (S)-2-[(S)-4-(tert-Butyl-diphenyl-silanyloxy)-2-triethylsilanyloxy-butyl]-oxirane which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 98.0%

: 994-30-9
triethylsilyl chloride

: 148586-01-0
(2S,4S)-(6-O-t-butyldiphenylsilyl)-1,2-epoxyhexa-4,6-diol

: 201868-03-3
(S)-2-[(S)-4-(tert-Butyl-diphenyl-silanyloxy)-2-triethylsilanyloxy-butyl]-oxirane

Guidance literature:: With N,N,N,N,-tetramethylethylenediamine; In N,N-dimethyl-formamide; Inert atmosphere;
DOI:10.1016/j.tet.2009.04.001

Reference yield:

: (S)-4-[2-(tert-Butyl-diphenyl-silanyloxy)-ethyl]-6-iodomethyl-[1,3]dioxan-2-one

: 201868-03-3
(S)-2-[(S)-4-(tert-Butyl-diphenyl-silanyloxy)-2-triethylsilanyloxy-butyl]-oxirane

Guidance literature:: Multi-step reaction with 2 steps

1: K₂CO₃ / methanol

2: 96 percent / TMEDA / dimethylformamide

With N,N,N,N,-tetramethylethylenediamine; potassium carbonate; In methanol; N,N-dimethyl-formamide;
DOI:10.1016/S0040-4039(97)10501-9

Reference yield: 65.0%

: 95452-06-5
tert-butyl(1,3-dithian-2-yl)dimethylsilane

: 192047-55-5
(R)-2,2-Dimethyl-4-((S)-2-methyl-oxiranylmethyl)-[1,3]dioxolane

: 201868-03-3
(S)-2-[(S)-4-(tert-Butyl-diphenyl-silanyloxy)-2-triethylsilanyloxy-butyl]-oxirane

: 625856-01-1
(2S,4S)-1-{2-[(S)-2-(tert-Butyl-dimethyl-silanyloxy)-3-((R)-2,2-dimethyl-[1,3]dioxolan-4-yl)-2-methyl-propyl]-[1,3]dithian-2-yl}-6-(tert-butyl-diphenyl-silanyloxy)-4-triethylsilanyloxy-hexan-2-ol

Guidance literature:: tert-butyl(1,3-dithian-2-yl)dimethylsilane; With tert.-butyl lithium; In diethyl ether; pentane; at -78 - -45 ℃; for 1h;

(R)-2,2-Dimethyl-4-((S)-2-methyl-oxiranylmethyl)-[1,3]dioxolane; In diethyl ether; pentane; at -78 - -25 ℃; for 1h;

(S)-2-[(S)-4-(tert-Butyl-diphenyl-silanyloxy)-2-triethylsilanyloxy-butyl]-oxirane; With N,N,N,N,N,N-hexamethylphosphoric triamide; In diethyl ether; pentane; at -78 - 20 ℃; for 2h;
DOI:10.1021/ja0376238