(Z)-(6S,7R)-6-Isopropenyl-7,11-dimethyl-2-phenylsulfanylmethyl-dodec-2-enoic acid ethyl ester

Base Information

Chemical Name:(Z)-(6S,7R)-6-Isopropenyl-7,11-dimethyl-2-phenylsulfanylmethyl-dodec-2-enoic acid ethyl ester
CAS No.:109308-08-9
Molecular Formula:C₂₆H₄₀O₂S
Molecular Weight:416.668
Hs Code.:

Synonyms:(Z)-(6S,7R)-6-Isopropenyl-7,11-dimethyl-2-phenylsulfanylmethyl-dodec-2-enoic acid ethyl ester

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Chemical Property of (Z)-(6S,7R)-6-Isopropenyl-7,11-dimethyl-2-phenylsulfanylmethyl-dodec-2-enoic acid ethyl ester

Chemical Property:

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Technology Process of (Z)-(6S,7R)-6-Isopropenyl-7,11-dimethyl-2-phenylsulfanylmethyl-dodec-2-enoic acid ethyl ester

There total 1 articles about (Z)-(6S,7R)-6-Isopropenyl-7,11-dimethyl-2-phenylsulfanylmethyl-dodec-2-enoic acid ethyl ester which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield:

: 20345-61-3
ethyl 2-diethoxyphosphinoylacrylate

: 930-69-8
sodium thiophenolate

: (4S,5R)-4-Isopropenyl-5,9-dimethyl-decanal

: 109308-07-8
(E)-(6S,7R)-6-Isopropenyl-7,11-dimethyl-2-phenylsulfanylmethyl-dodec-2-enoic acid ethyl ester

: 109308-08-9
(Z)-(6S,7R)-6-Isopropenyl-7,11-dimethyl-2-phenylsulfanylmethyl-dodec-2-enoic acid ethyl ester

Guidance literature:: Yield given. Multistep reaction. Yields of byproduct given; 1.) THF, 0 deg C, 10 min, 2.) THF, 2.5 h;
DOI:10.1021/jo00228a040

Reference yield: 100.0%

: 109308-08-9
(Z)-(6S,7R)-6-Isopropenyl-7,11-dimethyl-2-phenylsulfanylmethyl-dodec-2-enoic acid ethyl ester

: 109308-11-4
(Z)-(6S,7R)-6-Isopropenyl-7,11-dimethyl-2-phenylsulfanylmethyl-dodec-2-en-1-ol

Guidance literature:: With diisobutylaluminium hydride; In hexane; toluene; at -78 ℃; for 0.25h;
DOI:10.1021/jo00228a040

Reference yield:

: 109308-08-9
(Z)-(6S,7R)-6-Isopropenyl-7,11-dimethyl-2-phenylsulfanylmethyl-dodec-2-enoic acid ethyl ester

: 109308-14-7
(Z)-(6S,7R)-6-Isopropenyl-7,11-dimethyl-2-phenylsulfanylmethyl-dodec-2-enal

Guidance literature:: Multi-step reaction with 2 steps

1: 100 percent / diisobutylaluminium hydride / toluene; hexane / 0.25 h / -78 °C

2: pyridinium dichromate (PDC) / dimethylformamide / 2 h

With dipyridinium dichromate; diisobutylaluminium hydride; In hexane; N,N-dimethyl-formamide; toluene;
DOI:10.1021/jo00228a040