((Z)-(6S,7R)-6-Isopropenyl-7,11-dimethyl-2-vinyl-dodec-2-enylsulfanyl)-benzene

Base Information

• Chemical Name: ((Z)-(6S,7R)-6-Isopropenyl-7,11-dimethyl-2-vinyl-dodec-2-enylsulfanyl)-benzene
• CAS No.: 109308-16-9
• Molecular Formula: C₂₅H₃₈S
• Molecular Weight: 370.643

Synonyms:((Z)-(6S,7R)-6-Isopropenyl-7,11-dimethyl-2-vinyl-dodec-2-enylsulfanyl)-benzene

Chemical Property of ((Z)-(6S,7R)-6-Isopropenyl-7,11-dimethyl-2-vinyl-dodec-2-enylsulfanyl)-benzene

Chemical Property:

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Technology Process of ((Z)-(6S,7R)-6-Isopropenyl-7,11-dimethyl-2-vinyl-dodec-2-enylsulfanyl)-benzene

There total 2 articles about ((Z)-(6S,7R)-6-Isopropenyl-7,11-dimethyl-2-vinyl-dodec-2-enylsulfanyl)-benzene which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield:

sodium thiophenolate (930-69-8) → ((Z)-(6S,7R)-6-Isopropenyl-7,11-dimethyl-2-vinyl-dodec-2-enylsulfanyl)-benzene (109308-16-9)

Guidance literature:

Multi-step reaction with 4 steps

1: 1.) THF, 0 deg C, 10 min, 2.) THF, 2.5 h

2: 100 percent / diisobutylaluminium hydride / toluene; hexane / 0.25 h / -78 °C

3: pyridinium dichromate (PDC) / dimethylformamide / 2 h

4: dimethylsulfoxide / 6 h

With dipyridinium dichromate; diisobutylaluminium hydride; In hexane; dimethyl sulfoxide; N,N-dimethyl-formamide; toluene;

DOI:10.1021/jo00228a040

Reference yield:

(Z)-(6S,7R)-6-Isopropenyl-7,11-dimethyl-2-phenylsulfanylmethyl-dodec-2-enoic acid ethyl ester (109308-08-9) → ((Z)-(6S,7R)-6-Isopropenyl-7,11-dimethyl-2-vinyl-dodec-2-enylsulfanyl)-benzene (109308-16-9)

Guidance literature:

Multi-step reaction with 3 steps

1: 100 percent / diisobutylaluminium hydride / toluene; hexane / 0.25 h / -78 °C

2: pyridinium dichromate (PDC) / dimethylformamide / 2 h

3: dimethylsulfoxide / 6 h

With dipyridinium dichromate; diisobutylaluminium hydride; In hexane; dimethyl sulfoxide; N,N-dimethyl-formamide; toluene;

DOI:10.1021/jo00228a040

Reference yield: 80.0%

((Z)-(6S,7R)-6-Isopropenyl-7,11-dimethyl-2-vinyl-dodec-2-enylsulfanyl)-benzene (109308-16-9) → (3R,3aR)-3-((R)-1,5-Dimethyl-hexyl)-3a-methyl-7-phenylsulfanylmethyl-2,3,3a,4,5,7a-hexahydro-1H-indene (109308-21-6,109308-22-7)

Guidance literature:

With 2,5-bis(1,1-dimethylethyl)-1,4-benzenediol; In various solvent(s); for 2h; Heating;

DOI:10.1021/jo00228a040

upstream raw materials:

sodium thiophenolate

(Z)-(6S,7R)-6-Isopropenyl-7,11-dimethyl-2-phenylsulfanylmethyl-dodec-2-enoic acid ethyl ester

Downstream raw materials:

(3R,3aR)-3-((R)-1,5-Dimethyl-hexyl)-3a-methyl-7-phenylsulfanylmethyl-2,3,3a,4,5,7a-hexahydro-1H-indene

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